位置：成果数据库 > 期刊 > 期刊详情页
ABO3型钙钛矿结构的可见光光催化剂LaCo0.5Ti0.5O3的设计与合成
  • 期刊名称：高等学校化学学报, 2007, 28(3), 415-418. (SCI)
  • 时间：0
  • 分类：O614[理学—无机化学;理学—化学] O643.36[理学—物理化学;理学—化学]
  • 作者机构：[1]黑龙江大学化学化工与材料学院物理化学实验室,哈尔滨150080, [2]佳木斯大学化学与药学院,佳木斯154007
  • 相关基金：国家自然科学基金（批准号：20301006,20431030,20501007）、黑龙江省自然科学基金（批准号：ZJG04-04,B0305）和哈尔滨市青年科学基金（批准号：2005AFQXJ060）资助.
  • 相关项目：多孔钙钛矿型纳米材料的设计合成及光催化性能
关键词： 钙钛矿, LaCo0.5Ti0.5O3, 溶胶-凝胶法, 可见光光催化, Perovskite, LaCo0.5Ti0.5O3 , Sol-gel method, Visible light photocatalysis
中文摘要：

采用溶胶-凝胶法在较低温度条件下设计合成了新型的具有ABO3型钙钛矿结构的三元金属复合氧化物LaCo0．5Ti0.5O3．通过TG—DTA，XRD，XPS，UV—Vis DRS等测试技术和可见光光催化活性测试对其进行了表征．结果表明，与LaCoO3和La2Ti2O7相比，LaCo0．5Ti0.5O3样品表现出相对较高的可见光光催化活性，并且合成温度较低．这是由于原料中的Co^2＋和Ti^4＋离子通过电荷补偿作用使产物B位的两种金属均以＋3价氧化态分布所致．

英文摘要：

A novel ternary metal complex oxide, LaCo0.5Ti0.5O3, with ABO3-type perovskite structure was designed and synthesized by a sol-gel method at relatively low temperature, and were characterized by means of several testing techniques such as TG-DTA, XRD, XPS and UV-Vis DRS spectra. The results show that, compared with LaCoO3 and La2Ti2O7, the as-prepared sample exhibits a higher photocatalytic activity under visible light irradiation, and can be obtained at lower temperature. It can be proposed that the charge compensation effects make Co^2＋ and Ti^4＋ ions in raw material co-occupy uniformly B site in perovskite both as the forms of ＋ 3 valence, which is responsible for the lower temperature synthesis.

同期刊论文项目
钙钛矿型有机/无机杂化半导体材料的分子剪裁与组装
期刊论文 177 会议论文 30 著作 1
Ag(Cu)同步沉积与掺杂的TiO2的表面态和光电性质与光催
期刊论文 35
多孔钙钛矿型纳米材料的设计合成及光催化性能
期刊论文 30 会议论文 7 著作 1
同项目期刊论文
Study on the mechanisms of photoinduced carriers separation and recombination for Fe3+–TiO2 photocat
ZnO纳米棒阵列的同步法制备及其PL性能研究
纳米LaFeO3的制备和表征及其气相光催化性能
DBS包覆TiO2纳米粒子的制备、表征及其相转移
Enhanced photocatalytic activity of S-doped TiO2–ZrO2 nanoparticles under visible-light irradiation
Synthesis and photocatalytic activity of stable nanocrystalline TiO2 with high crystallinity and lar
Review of photoluminescence performance of nano-sized semiconductor materials and its relationships
Superhydrophilic anatase TiO2 film with the micro- and nanometer-scale hierarchical surface structur
Effects of doping La and Cu on photoinduced charge properties of TiO2 and its relationships with pho
表面修饰DBS基团对TiO2气相光催化性能的影响
磷酸对TiO2纳米粒子光催化剂的改性
多孔SiO2与TiO2复合纳米材料的制备及光催化性能
Effects of Sn dopant on the photoinduced charge property and photocatalytic activity of TiO2 nanopar
不同方法制备的TiO2薄膜电极光电性能比较
La和Cu掺杂对纳米TiO2光生电荷性质的影响及其与光催化活性的关系
不同晶相组成TiO2纳米粒子的拉曼光谱表征及其光催化性能
Investigation on the electron transfer between anatase and rutile in nano-sized TiO2 by means of sur
Enhancement of the photocatalytic activity of TiO2 nanoparticles by surface-capping DBS groups
Preparation and characterization of stable biphase TiO2 Photocatalyst with high crystallinity, large
Enhanced activity of bismuth-compounded TiO2 nanoparticles for photocatalytically degrading rhodamin
Photoinduced charge property of nanosized perovskite-type LaFeO3 and its relationships with photocat
Effects of noble metal modification on surface oxygen composition, charge separation and photocataly
Effects of surface oxygen vacancies on photophysical and photochemical processes of Zn-doped TiO2 na
Mesoporous SiO2-modified nanocrystalline TiO2 with high anatase thermal stability and large surface
基于一维有序阵列的新型纳米结构半导体膜的设计合成及光催化性能
Effects of the addition of Zn2+ and sodium dodecylbenzenesulfonate groups on the photocatalytic and
Controllable vertical growth onto anatase TiO2 nanoparticle films of ZnO nanorod arrays and their ph
Eu2O3修饰对纳米TiO2热稳定性及光催化活性的影响
Synthesis and characterization of spherical Sr2CeO4 phosphors by spray pyrolysis for field em
Photoluminescent properties of sol-gel derived (La, Gd)MgB5O10: Ce3+/Tb3+ nanocrystalline thin films
Monodisperse Spherical Core-Shell Phosphors Obtained by Functionalization of Silica Spheres with Y2O
Sol-gel synthesis and characterization of Zn2SiO4: Mn@SiO2 spherical core-shell particles
Hydrothermal synthesis of SrCO3:Eu3+ / Tb3+ microneedles and their luminescence properties
Synthesis, Structure and Optical Properties of Different Dimensional Organic-Inorganic Perovskites
Luminescence Properties of Y0.9-xGdxEu0.1Al3(BO3)4 (0≤ x ≤0.9 ) Phosphors Prepared by Spray Pyrol
Synthesis and Luminescent Properties of Europium (III) Schiff Base Complexes Covalently Bonded to Si
A Novel and Efficient Route to Se Nano/Microstructures with Controllable Phase and Shape
Preparation of TiO2 nanocrystallites by hydrolyzing with gaseous water and their photocatalytic acti
Synthesis and structure of new low dimensional polymeric haloplumbates (II) complexes (C40H40N8)Pb4B
Phase Transformation and Photoluminescence Properties of Nanocrystalline ZrO2 Powders Prepared by P
Polyol-Mediated Synthesis of PbS Crystals: Shape Evolution and Growth Mechanism
Enchanced Photoluminescence of Ga2O3: Dy3+ Phosphor Films by Li Doping
Synthesis and Characterization of Co(II)Salen Functionalized MCM-41-Type Hybrid Mesoporous Silicas a
Study of Quasi - Monodisperse In2O3 Nanocrystals:Synthesis and Optical Determination
Silica Spheres Coated with YVO4:Eu3+ Layers via Sol-Gel Process: A Simple Method to Obtain Spherical
Magnetic Mesoporous Silica Spheres for Drug Targeting and Controlled Release
Two-Dimensional β-NaLuF4 Hexagonal Microplates
Host sensitized luminescence of Dy3+ in nanocrystalline β-Ga2O3 prepared by a Pechini-type sol-gel p
Facile Synthesis and Characterization of Single Crystalline Bi2S3 with Various Morphologies
Synthesis, Structure and Optical Properties of A Contorted <110>-Oriented Layered Hybrid Perovskite:
Polyol-mediated synthesis and photoluminescent properties of Ce3+ and/or Tb3+-doped LaPO4 nanopartic
Synthesis and characterization of monodisperse spherical core-shell structured SiO2@Y3Al5O12:Ce3+/ T
Enhanced luminescence of gadolinium niobates by Bi3+ doping for field emission displays
Large-Pore Mesoporous Nanocrystalline Titania Thin Films Synthesized through Evaporation-Induced Sel
Preparation of large-pore mesoporous nanocrystalline TiO2 thin films with tailored pore diameters.
Effects of Simultaneously Doped and Deposited Ag on the Photocatalytic Activity and Surface States o
Biofunctionalization of CeF3:Tb3+ Nanoparticles
Tunable Luminescence Properties of Tb3+-doped LaGaO3 nanocrystalline phosphors
Host-Sensitized Luminescence of Dy3+, Pr3+, Tb3+ in Polycrystalline SrIn2O4 for Field Emission Displ
Spherical SiO2@GdPO4:Eu3+ Core-Shell Phosphors: Sol-gel Synthesis and Characterization
Nanostructured CaWO4, CaWO4: Pb2+ and CaWO4: Tb3+ particles: polyol-mediated synthesis and luminesce
Host-sensitized luminescence of Dy3+, Pr3+, Tb3+ in polycrystalline CaIn2O4 for field emission displ
Enhanced photoluminescence of Ba2GdNbO6:Eu3+/Dy3+ phosphors by Li+ doping
Synthesis and luminescent properties of Lu3Ga5O12: RE3+ (RE = Eu, Tb and Pr) nanocrystalline phospho
Spindle-like Lanthanide Orthovanadate Nanoparticles: Facile Synthesis by Ultrasonic Irradiation, Cha
Structural and Bluish-White Luminescent Properties of Li+-doped BPO4 as a Potential Environmentally-
Pechini sol-gel deposition and luminescence properties of Y3Al5-xGaxO12:Ln3+ (Ln3+= Eu3+, Ce3+, Tb3+
Nanostructured CaWO4, CaWO4: Eu3+ and CaWO4:Tb3+ Particles: Sonochemical Synthesis and Luminescent P
Mesoporous silica coated CeF3:Tb3+ particles for drug release,
Tunable Luminescence Properties of CaIn2O4: Eu3+ Phosphors
Enhanced activity of bismuth- compounded TiO2 nanoparticles for photocatalytically degrading rhodami
ABO3型钙钛矿结构的可见光光催化剂LaCo0.5Ti0.5O3的设计与合成.
ITO/TiO2表面电沉积CdS纳米粒子及薄膜的光电性能.
表面修饰DBS基团对TiO2气相光催化性能的影响.
Synthesis and Characterization of Urea Bridged Hybrid Periodic Mesoporous Organosilica Materials
La和Cu掺杂对纳米TiO2光生电荷性质的影响及其与光催化活性的关系.
改性中孔分子筛SBA-16薄膜的合成及表征.
一系列d8配合物1,3[(dz2)(pz)]激发态和金属间相互作用的理论研究.
Photocatalytic activity and interfacial carrier transfer of Ag–TiO2 nanoparticle films.
Uniform TiO2 thin films with anatase nanocrystallites synthesized through evaporation-induced assemb
Highly Uniform and Monodisperse Ba2ClF3 Microrods: Solvothermal Synthesis and Characterization
New Organic-Inorganic Perovskite Materials with Different Optical Properties Modulated by Different
Sol-gel deposition and luminescence properties of LiYF4:Tb3+ thin films
Pechini sol-gel deposition and luminescent properties of Eu3+, Tb3+ -doped SrLaGa3O7 phosphor films
ZnO和TiO2纳米粒子的光致发光性能及其与光催化活性的关系.
纳米Au/TiO2光催化剂的XPS和SPS研究.
A theoretical probe on the ground- and excited-state properties of heterobinuclear Au–Pt complex wit
A first-principles investigation into the ferroelectric and antiferrodistortive instabilities of cub
Solvent Induced Different Morphologies of Bis(propyl) triethoxysilane Substituted Perylenediimide a
Controllable Synthesis of Graphitic Carbon Nanostructures from Ion-Exchange Resin-Iron Complex via S
Preparation, characterization, and photo-induced hydrophilicity of nanocrystalline anatase thin film
A simple and large-scale strategy for the preparation of Ag nanoparticles supported on resin-derived
Enhancement of the photocatalytic activity of TiO2 nanoparticles by surface-capping DBS groups.
Preparation and photoelectric performance of ITO/TiO2/CdS composite thin films.
Facile synthesis of iron oxide with wormlike morphology and their application in water treatment.
Layered Organic - inorganic Perovskite-type Hybrid Materials Fabricated by Spray Pyrolysis Route
Morphology control and luminescence properties of YVO4: Eu3+ phosphors prepared by spray pyrolysis
Synthesis and Characterization of Magnetic FexOy@SBA-15 Composites with Different Morphologies for C
Fabrication, characterization of spherical CaWO4:Ln@MCM-41 (Ln= Eu3+, Dy3+, Sm3+, Er3+) composites a
Comparative Study of Ga2O3:Dy3+ Phosphors Prepared by Three Methods
Synthesis, Structure and Optical Properties of New Organic-Inorganic Haloplumbates complexes (C5H10N
Hydrothermal synthesis and luminescent properties of LuBO3:Tb3+ microflowers
One-Step Synthesis and Luminescent Properties of Nanocrystalline YVO4:Eu3+ powders
Self-Directed Assembly of Photoactive Perylenediimide-Bridged Silsesquioxane into Superlong Tubular
Sol-gel synthesis and characterization of SiO2@NaGd(WO4)2:Eu3+ core-shell structured spherical phosp
Mesoporous TiO2/α-Fe2O3: Bifunctional Composites for Effective Elimination of Arsenite Contamination
Sol-gel growth of Gd2MoO6:Eu3+ nanocrystalline layers on SiO2 spheres (SiO2@Gd2MoO6:Eu3+) and their
纳米LaFeO3的制备和表征及其气相光催化性能
表面修饰DBS基团对TiO2气相光催化性能的影响
不同晶相组成TiO2纳米粒子的拉曼光谱表征及其光催化性能
LaGaO3: A (A= Sm3+ and/or Tb3+) as promising phosphors for field emission displays
Shape Controllable Synthesis and Upconversion Properties of NaYbF4 / NaYbF4:Er3+ and YbF3 / YbF3: Er
Uniform Colloidal Alkaline Earth Metal Fluoride Nanocrystals: Nonhydrolytic Synthesis and Luminescen
Monodisperse Core-Shell Structured SiO2@YBO3:Eu3+Spherical Particles: Synthesis and Characterization
Bioactive, Luminescent and Mesoporous Europium-doped Hydroxyapatite as a Drug Carrier
Sol-Gel-Derived BPO4/Ba2+ as a New Efficient and Environmentally-Friendly Bluish-White Luminesc
Novel < 110 > - Oriented Organic-Inorganic Perovskite Compound Stabilized by N- (3- Amino propyl ) -
Tunable photoluminescent and cathodoluminescent properties of ZnO and ZnO:Zn phosphors
In(OH)3 and In2O3 nanorod bundles and spheres: microemulsion-mediated hydrothermal synthesis and lum
Self-Assembled 3D Architectures of LuBO3:Eu3+ : Phase Selective Synthesis, Growth Mechanism and Tuna
Preparation and Luminescence Properties of YVO4:Ln and Y(V, P)O4: Ln (Ln = Eu3+, Sm3+, Dy3+) Nanofib
Hydrothermal Synthesis of Lanthanide Fluorides LnF3 (Ln = La-Lu) Nano / Microcrystals with Multiform
Fabrication of Self-assembled Palladium Nanosheets Using Layered Organic/inorganic Hybrid as Templat
Sol-Gel Synthesis and Photoluminescence Properties of Spherical SiO2@LaPO4: Ce3+/Tb3+ Particles with
Dy3+ and Eu3+-doped LaGaO3 nanocrystalline phosphors for field emission displays
One-step Aqueous Solvothermal Synthesis of In2O3 Nanocrystals
Enhanced Luminescence of BPO4 by Mixing with SiO2 and Al2O3
Y2O3 Micro/Nanoprisms with Trilobal Cross Section
Simple synthesis of mesoporous alumina thin films.
Monodisperse spherical core-shell structured SiO2-CaTiO3:Pr3+ phosphors for field emission displays
Size-Tailored Synthesis and Luminescent Properties of One Dimensional Gd2O3:Eu3+ Nanorods and Micror
Enhanced photocatalytic activity of S-doped TiO2-ZrO2 nanoparticles under visible-light irradiation.
Facile synthesis of ordered nanocrystalline alumina thin films with tunable mesopore structures.
Spin-coating preparation of highly ordered photoluminescent film of layered PbI2-aminoalkyloxysilane
Luminescent properties of R2MoO6:Eu3+ (R=Gd3+, Y3+, La3+) phosphors prepared by Pechini sol-gel proc
Growth and optical properties of nanocrystalline Gd3Ga5O12:Ln (Ln= Eu3+, Tb3+, Er3+) powders and thi
A simple method to synthesize GaOOH and β-Ga2O3 nanorods and their luminescent properties
Photoluminescence of sol-gel derived (Y, Gd) BO3 thin film phosphors doped with Eu3+ and Tb3+
Controlled growth of mesostructured crystalline iron oxide nanowires and Fe-filled carbon nanotube a
First-Principles Investigation of Stability and Structural Properties of the BaTiO3 (110) Polar Surf
Assembly of β-Cyclodextrins Acting as Molecular Bricks onto the Multiwall Carbon Nanotubes.
Hydrophilicity and formation mechanism of large-pore mesoporous TiO2 thin films with tunable pore di
Influence of calcination temperatures on the photocatalytic activity and photo-induced hydrophilicit
Multi-modal mesoporous TiO2–ZrO2 composites with high photocatalytic activity and hydrophilicity.
Solvothermal Synthesis of Well-dispersed MF2 (M= Ca, Sr, Ba) Nanocrystals and their Optical Properti
一系列d^8配合物^1,3[（dz^2）（Pz）]激发态和金属间相互作用的理论研究
ITO/TiO2表面电沉积CdS纳米粒子及其薄膜的光电性能
电泳沉积法制备介孔TiO2／单壁碳纳米管薄膜
电沉积法制备介孔TiO2／CdS薄膜光电极
电沉积条件对ITO／TiO2／CdS薄膜光电性能的影响
Eosin Y/有序二氧化硅复合体的光致发光性质研究
LaPO4：Eu^3＋纳米粒子的多醇法合成及其光致发光性能研究
稀土氟化物纳／微米材料的水热合成、形成机理和发光性质
二（正丁基）花四酰二亚胺微纤的制备及其发光性质
TiO2纳米粒子的表面光电压与光催化活性的关系
SrZrO3晶格动力学的密度泛函理论研究
阳离子表面活性剂（CTAB）修饰TiO2的光催化性能研究
多孔TiO2粉体的水热合成及其光催化性能
胶溶-水热法制备超细PAA/TiO2纳米粉体的研究
不同产地防风中挥发油成分分析
Comparative study on photocatalytic prepared in acidic medium and basic properties of TiO2 nanoparticles medium by hydrothermal method
Photogenerated carrier transfer mechanism and photocatalysis properties of TiO2 sensitized by Zn（ Ⅱ ） phthalocyanine
A theoretical study on the rad
Looking for the stable isomers
Investigations on the surface
Uniform TiO2 thin films with a
Deactivation and regeneration
Preparation of Large-Pore Meso
Influence of calcination tempe
Large-pore mesoporous nanocrys
Predicting potential stable is
Hydrophilicity and formation m
Effects of noble metal modific
Structure and stability of the
Photocatalytic activity and in
The preparation and characteri
Effects of Sn dopant on the ph
A Combined Density Functional
Effects of Simultaneously Dope
Controlled growth of mesostruc
Fe3+-TiO2/SiO2气相光催化降解乙
纳米LaFeO3的制备和表征及其气相光催化性能
钛酸铅及钛酸钡的电子结构和铁电相变的密度泛函理论研究
SrZrO3晶格动力学的密度泛函理论研究
HF与HOBO反应速率常数的TST理论研究
NCCS^＋,CNCS^＋和CCNS^＋异构体结构的密度泛函与耦合簇方法研究
苝四羧酸酰二亚胺染料系列光电性能的研究
5-yl-pent-1-ene自由基环合成反应机理的理论研究
6-yl—hex-1-ene自由基环合成反应机理的理论研究
几个碳单环及双环分子环应力的理论研究
sp^3杂化碳中心自由基进攻腈基环合成反应的理论研究
CP与C2H2^＋自由基-离子反应机理与产物分布的理论研究