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水性异氰酸酯交联剂/VAE复合胶粘剂的制备与应用
  • 期刊名称:中国胶粘剂
  • 时间:0
  • 页码:31-34
  • 分类:TQ436.5[化学工程] TQ433.43
  • 作者机构:[1]教育部轻化工助剂化学与技术重点实验室,陕西科技大学,陕西西安710021
  • 相关基金:国家自然科学基金项目(50973057);陕西省13115重点科技项目(2008ZDKG-51).
  • 相关项目:反应性丙烯酸树脂无皂乳液/封闭异氰酸酯复合板防水黏结剂制备关键技术及应用基础研究
中文摘要:

将六亚甲基二异氰酸酯(HDI)三聚体在自制的丙烯酸树脂乳液中乳化,制得水性异氰酸酯交联剂乳液;然后将交联剂乳液与VAE乳液(醋酸乙烯-乙烯共聚乳液)复配,制得木材用胶粘剂。结果表明:当m(丙烯酸树脂):m(异氰酸酯)=2:1、m(水性异氰酸酯交联剂乳液):m(VAE乳液)=1:2、施胶量为300g/m。和热压温度为110~130℃时,细木工板的胶接强度(085MPa)、横向静曲强度(22.6MPa)和耐水性(80℃热水中浸泡10h不开胶)均达到较佳值,并且均符合GB/T9846-2004标准。

英文摘要:

A water-based isocyanate cross linker emulsion was prepared when hexamethylene diisocyanate(HDI) tripolymer was emulsified in self-made acrylic ester resin emulsion. Then an adhesive for wood was prepared by mix between the cross linker emulsion and VAE emulsion (vinyl acetate-ethylene copolymer emulsion ). The results showed that the bonding strength (0.85 MPa),the transverse static bending strength (22.6 MPa) and water resistance(not glue failure in 80 ℃ hot water for 10 hours) could all reach optimal values,and could all meet standards of GB/T 9 846-2004 for blockboard when mass ratio of m (acrylic ester resin):m (isocyanate) was 2:1, mass ratio of m(water-based isocyanate cross linker emulsion):m(VAE emulsion) was 1:2, adhesive content was 300 g/m^2 and hot pressing temperature was 110-130℃.

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