中文摘要：

合成了三种含有四苯基乙烯结构的双炔烃．这些双炔烃单体通过在CuCl催化下在邻二氯苯中进行的均聚反应可以高产率地生成线型聚炔．所得聚合物均可很好地溶解于常见有机溶剂中，并具有很高的热稳定性．这类聚炔材料在溶液态时几乎不发光，但在聚集态或者固态下可高度发光，表现出典型的聚集诱导发光性质．同时，这些聚合物具有高透光性，可以允许整个可见光区的光透过．其薄膜在4001700nm宽波长范围内表现出高折射率（n=1．7787-1．6543）和低色差（D＇=0．0003）．紫外光照射可诱使聚合物薄膜发生交联过程，从而调控其折射率数值，并可生成高分辨率的荧光图案．

英文摘要：

Tetraphenylethene-containing diacetylenes are synthesized and their homopolymerizations are catalyzed by CuCl in o-dichlorobenzene, furnishing linear polyynes in high isolated yields. All polymers possess good solubility in common organic solvents and enjoy high thermal stability. Whereas they are practically non-emissive when molecularly dissolved in good solvents, they become highly emissive when aggregated as nanoparticle suspensions in poor solvents or fabricated into thin films in the solid state, demonstrating a novel phenomenon of aggregation-induced emission. The polymers are highly transparent, allowing almost all light in the entire visible spectral region to transmit through. Thin films of the polymers show high refractive indices （n= 1.7787- 1.6543） in the wavelength region of 400- 1700 nm and very low chromatic aberrations （D＇=0.0003）. Their n values can be modulated and their thin films can be crosslinked by UV irradiation, generating fluores- cent patterns with high resolutions.