位置:成果数据库 > 期刊 > 期刊详情页
Adsorption and Desorption Behavior of Tannic Acid in Aqueous Solution on Polyaniline Adsorbent
  • ISSN号:1004-9541
  • 期刊名称:Chinese Journal of Chemical Engineering
  • 时间:2013.6
  • 页码:594-599
  • 分类:O647.33[理学—物理化学;理学—化学] TS262.5[轻工技术与工程—发酵工程;轻工技术与工程—食品科学与工程]
  • 作者机构:[1]Colleze of Resource and Environment, Shaaaxi University of Science & Technology, Xi'an 710021, China, [2]Key Laboratory of Auxiliary Chemistry and Technology for Chemical Industry, Ministry of Education, College ofChemistry and Chemical Engineering, Shaanxi University of Science & Technology, Xi'an 710021, China
  • 相关基金:Supported by the National Major Research Plan for Water Pollution Control and Treatment of China (2008ZX07010-003-002), the National Natural Science Foundation of China (21107065) and the Scientific Research Program Funded by Shaanxi Pro- vincial Education DePartment (HJK0769).
  • 相关项目:磁性纳米吸附剂对腐殖酸、重金属复合污染的共吸附机理研究
中文摘要:

鞣质的酸通常被看作 polyphenolic 污染物质之一,它可以引起严重威胁到环境。在这研究, polyaniline 吸附物被化学氧化综合在水的答案移开鞣质的酸。与溶液和强壮的吸附的 pH 极大地改变的鞣质的酸的吸附数量在 pH 5.86.7。共存的阳离子例如 Na+ , K+ ,和 Ca2+ ,能在 polyaniline 上提高鞣质的酸的吸附,它可以被贡献在鞣质的酸和 polyaniline 之间的静电的相互作用。吸附过程能被兰米尔模型很好描述,最大的吸附能力是 117.65 mg 据敲獡獥漠 ? 敭湡丠獵敳瑬渠浵敢 ? 映楲瑣潩 ? 慦瑣牯愠摮琠敨浲污瀠牥潦浲湡散 ? 湩琠敨琠'T? 煥極灰摥眠瑩 ? 潣扭湩摥搠癥捩獥 ? 敲灳 ' 虡 N敶祬?牡??????┸愠摮??‥癯牥琠潨敳椠?桴?畴敢眠瑩?桴?剃?污湯吗?

英文摘要:

Tannic acid is generally considered as one of polyphenolic pollutants, which may cause severe threats to the environment. In this study, polyaniline adsorbent was synthesized by chemical oxidation to remove tannic acid in aqueous solutions. The adsorption amount of tannic acid varied greatly with pH of solution and strong adsorption was at pH 5.8-6.7. Coexisting cations, such as Na+, K+, and Ca2+, can enhance the adsorption of tannic acid on poly- aniline, which may be contributed to the electrostatic interaction between tannic acid and polyaniline. The adsorp- tion process could be well described by Langmuir model and the maximum adsorption capacity was 117.65 rag.g〈 at 35℃and pH 6.0. The thermodynamic parameters calculated from the adsorption isotherms indicate that the ad- sorption of tannic acid is spontaneous and endothermic process. The polyaniline saturated with tannic acid can be desorbed in alkaline solution and regenerated adsorbent can be used repeatedly with high adsorption capacity, which implies that polyaniline adsorbents have a great potential in water purification for the removal of tannic acid.

同期刊论文项目
同项目期刊论文
期刊信息
  • 《中国化学工程学报:英文版》
  • 中国科技核心期刊
  • 主管单位:中国科协
  • 主办单位:中国化学工业与化学工程学会
  • 主编:
  • 地址:北京东城区青年湖路13号
  • 邮编:100011
  • 邮箱:cjche@cip.com.cn
  • 电话:010-64519487/88
  • 国际标准刊号:ISSN:1004-9541
  • 国内统一刊号:ISSN:11-3270/TQ
  • 邮发代号:
  • 获奖情况:
  • 1998年化工系统优秀信息成果一等奖,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,美国科学引文索引(扩展库),英国高分子图书馆,日本日本科学技术振兴机构数据库,中国中国科技核心期刊
  • 被引量:385