中文摘要：

以Na2WO4·2H2O和HCl为原料，采用水热法合成了WO3，并用x射线粉末衍射（XRD）、扫描电镜（SEM）、紫外漫反射（uV—Vis）、电子能量分散谱（EDS）和激光拉曼光谱（Raman）测试手段对样品进行表征。测试结果表明，Na2SO4作为添加剂时水热合成的产物皆为六方相三氧化钨纳米线，其粗细和长短略有差异，不同浓度的Na2SO4对产品晶型和形貌无影响，但影响其晶粒尺寸，其中0．125MNa2SO4所得六方相WO3纳米线的尺寸最小，平均直径约为5nm，长度约为1um，并具有最佳的光催化活性，可见光（≥420nm）照射150min罗丹明B溶液后的降解率达96．01％。

英文摘要：

WO3 were prepared by hydrothermal method using Na2WO4·2H20 and HC1 as raw materials. The samples were character- ized by X-ray diffraction （ XRD ）, scanning electron microscope （ SEM ）, and UV-Vis diffusion reflectance spectra （ UV-vis ）, electron energy spectrum dispersion （EDS） and laser Raman spectroscopy （Raman） measurements. The results show that the products via hy- drothermal process are hexagonal WO3 nanowires with Na,2SO4 as additive, and the thickness and length of nanowires have a slight difference, suggesting that different concentrations of Na2SO4 have certain influence on the grain size, but no effect on the crystal form and morphology. Photocatalytic degradation of rhodamine B solution （ 1×10^-4mol/L） show that hexagonal WO3 nanowires prepared in the presence of 0. 125 M NazSO4 has smallest size, the average diameter and length of the sample are respectively 5 nm and 1 urn, exhibiting the best photocatalytic activity, and its degradation rate of rhodamine B solution is 96. 01% under visible-light irradiation （≥ 420 nm） after 150 min.