本文重点关注预测层流火焰速度和反应中关键组分的演变过程,采用一种实用的思路构建了一个的异辛烷化学动力学骨架模型,包含32种组分和111个反应。基于骨架模型的构建目标,将异辛烷的燃烧过程考虑为以下两个部分:一部分是详细的小分子机理,它作为整个机理的“内核”,详尽地描述了着火以后的反应过程和特性;另一部分是通过耦合“内核”来专门描述和控制着火特性的骨架模型。新的骨架模型分别采用激波管、喷射搅拌反应器、流动反应器、层流火焰速度和HCCI发动机进行了验证,均显示出很好的性能。
Focusing on predicting laminar flame speed and important species evolution, a skeletal chemical kinetic model for iso-octane oxidation is constructed by using a practical methodology. The new model consists of 32 species and 111 reactions. Based on the skeletal model target, the methodology considers a combustion mechanism as two parts: a comprehensive part describing reaction processes involving small radicals and molecules as the 'core', and a skeletal one which, in coupling with the 'core', controls the ignition characteristics. The new iso-octane model has been validated against various experimental data including shock tube, jet-stirred reactor, flow reactor, laminar flame speed and HCCI engine, and shows good performance in all the cases.