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MgB2中的MgO纳米管
  • 期刊名称:低温物理学报Vol.29(2),(2008)第98-101页。
  • 时间:0
  • 分类:TQ174.758[化学工程—陶瓷工业;化学工程—硅酸盐工业]
  • 作者机构:[1]北京大学物理学院、人工微结构与介观物理国家重点实验室,北京100871
  • 相关基金:国家“973”计划(项目编号:2006-CD-601004)和国家自然科学基金(项目编号:50572001)资助的课题.
  • 相关项目:物理化学气相沉积法生长MgB2厚膜的研究
中文摘要:

为观察MgO在MgB2超导样品中的影响和存在形式,通过在MgB2胚体样品之外,增加周围MgO量的实验方法,经过4 h 750℃的烧结,在制备好的MgB2超导样品内得到了壁厚是约4纳米,直径在50~80纳米,长为30~40微米以上的氧化镁(MgO)纳米管.在MgB2样品表面可以看到少量直径是200~300纳米的氧化镁(MgO)亚微米线.经过扫描电镜的能量损失谱和透射电镜EELS分析测量,证明了纳米管中没有硼元素.实验观测也表明这些氧化镁(Mgo)纳米管是由许多氧化镁(MgO)纳米晶片组成.

英文摘要:

In order to observe the influence and the existence of MgO in MgB2 superconductor samples, the extra MgO was introduced around the MgB2 embryo. After sintered the sample for 4 hours at 750℃, the nano-MgO tubes, with diameter are 50 ~ 80 nanometers, lengths are 30 ~ 40μm, and wall thickness are about 4 nanometers, were obtained in the MgB2 sample, There is some nano-MgO fibers with diameters are 200 ~300 nanometers existed on the sample surface. They are sub-micron wires. By the SEM EELS survey and TEM EELS analysis, we can confirm that the nano-MgO tubes do not contain B. And the experiment observation also indicated that the nano-MgO tubes constitute of many MgO nanometer crystal pieces. So nano-MgO tubes are polycrystalline.

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