采用沉淀-浸渍法合成了一种新型La^3+和S共掺杂TiO2纳米复合光催化剂。通过紫外.可见(UV-Vis)漫反射、X射线衍射(XRD)和透射电子显微镜(TEM)等手段对其物相组成、晶粒尺寸、结晶形态和吸光性能进行了表征。以活性艳蓝198染料溶液为模拟废水,对La^3+/S/TiO纳米复合光催化剂的活性进行了评价。相对于单一的TiO2,S掺杂的TiO2和La^3+掺杂的TiO2光催化剂,La^3+/S/TiO2纳米复合光催化荆颗粒的粒径更小,光的吸收边发生了更大程度的红移。在波长λ〉400nm的可见光光照下,具有最高的光催化活性。
A novel La^3+/S/TiO2 nanocomposition photocatalyst was prepared by precipitation-doping method. UV-Vis diffuse reflection spectra (DRS), X-ray diffraction (XRD) and transmission electron microsco- py (TEM) were employed to characterize the optical characteristics, crystal and particle size and the phase composition of the sample. The photocatalytic activities of La^3+/S/TiO2 were evaluated using the photodegradation of reactive blue 198 as a probe reaction under the irradiation of xenon light. Compared with pure TiO2, S-doped TiO2 and La^3+ -doped TiO2, the sizes of La^3+/S/TiO2 are smaller, and the absorption edge shifts remarkably toward longer wavelength. Under the irradiation of visible light (A 〉 400 nm), La^3+/S/TiO2 have the maximum photocatalytic activity.