通过Suzuki聚合反应合成了一系列以芴-alt-咔唑为主链,铱配合物为侧链的深红色电磷光共轭聚合物.发光器件结构为ITO/PEDOT:PSS/PVK/Copolymer/Ba/Al,基于共聚物PFCzIrNiq—1的器件在电流密度为9.4mA/cm^2时,最大外量子效率为0.23%,最大发射波长为680nm.
A novel monomer derived from dibromocarbazole with N-grafted with Ir complex by a long alkyl side chain was synthesized. Based on this new monomer, a series of poly (fluorene-ah-carbazole) s which tethered red light-emitting Ir complex as emitting center were synthesized with Suzuki polycondensation. The polymer light-emitting diodes with structure of ITO/PEDOT: PSS/PVK/Copolymer/Ba/Al were prepared based on the resulted copolymers. The copolymer PFCzIrNiq-1 exhibits maximal quantum efficiency of 0. 23% at 9.4 mA/cm^2. The peak emission of the resulted copolymers was at 680 nm, which was among the reported deepest iridium containing red-light-emitting electrophosphorescent polymers.