中文摘要：

水热合成了介孔材料MCM-41，并以其为载体负载固体超强酸SO4^2-／ZrO2，通过XRD和N2吸附／脱附对制备的SO4^2-／ZrO2／MCM-41催化剂进行了表征。在固定床反应器中．以丙烯和乙酸为原料，研究了该催化剂合成乙酸异丙酯的活性。对反应条件进行了系统考察。得出了最佳的反应条件：反应温度140℃；反应压力1．2MPa；空速（LHSV）1．0h^-1；n（C3H6）：n（CH3COOH）=3：1。在此条件下，乙酸异丙酯的产率最高可达68．9％。同时，通过48h的催化剂寿命实验，结果表明谊催化剂具有较好的稳定性。

英文摘要：

Solid superacid SO4^2-/ZrO2 was loaded on the surface of MCM-41, which was prepared by hydrothermal methods. The SO4^2-/ZrO2/MCM-41 catalysts were characterized by XRD and N2 adsorption/ desorption techniques. The catalytic activity of SO4^2-/ZrO2/MCM-41 for synthesis of isopropyl acetate from propylene and acetic acid was studied in fixed-bed reaction system. The reaction conditions were inspected in detail and the optimum reaction conditions were obtained, that is, reaction temperature is 140℃ ; reaction pressure is 1.2 MPa;space velocity （LHSV） is 1.0 h^-1 ; n （C3H6） ： n（CH3COOH） = 3 ： 1. Under these conditions, the yield of isopropyl acetate is up to 68.9 %. At the same time,as is known that the catalysts possess quite good stability through 48 h lifetime experiment.