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SBA-15负载多吡啶铂（Ⅱ）配合物光催化1，4-二氢吡啶衍生物的芳香化反应
  • ISSN号：1674-0475
  • 期刊名称：《影像科学与光化学》
  • 时间：0
  • 分类：O64[理学—物理化学;理学—化学]
  • 作者机构：[1]中国科学院理化技术研究所,光化学转换与功能材料重点实验室,北京100190, [2]中国科学院研究生院,北京100049
  • 相关基金：科技部国家重点基础研究发展计划项目（2006CB816105;2007CB808004;2007CB936001）;国家自然科学基金资助项目（20732007;20728506;20672122）.
作者： 徐红霞[1,2], 陈彬[1], 吴骊珠[1], 佟振合[1]
关键词： 三联吡啶铂(Ⅱ)配合物, 介孔分子筛, 汉斯酯1, 4-二氢吡啶, 光催化芳香化, platinum （ Ⅱ） terpyridyl complex, SBA- 15 , 1,4- dihydropyridine, photocatalytic aromatization
中文摘要：

本文通过氨基的配位作用将三联吡啶铂（Ⅱ）配合物[Pt（L）Cl]Cl固载到SBA-15分子筛的表面，利用SBA-15负载催化剂完成了可见光（λ〉400nm）催化1，4-二氢-3，5-二甲酸乙酯-2，4，6-三甲基吡啶的芳香化反应．芳香化反应产物单一，并在反应体系中检测到了氢气的生成．反应结束后，只需简单的过滤即可实现催化剂的回收利用．

英文摘要：

Platinum（Ⅱ） terpyridyl complex incorporated into the channels of SBA-15 has been used as a photocatalyst for aromatization of 1,4-dihydro-3,5-diethyl dicarboxylates-2,4,6- trimethylpyridine. Upon irradiation, the photochemical aromatization takes place without additional oxidant, accompanied by the hydrogen production. The immobilized catalyst can be simply recycled by filtration.

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期刊信息
  • 《影像科学与光化学》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国科学院理化技术研究所 中国感光学会
  • 主编：佟振合
  • 地址：北京市海淀区中关村东路29号中国科学院理化技术研究所
  • 邮编：100190
  • 邮箱：xb@mail.ipc.ac.cn
  • 电话：010-82543683
  • 国际标准刊号：ISSN：1674-0475
  • 国内统一刊号：ISSN：11-5604/O6
  • 邮发代号:2-383
  • 获奖情况:
  • 中国科技核心期刊,《中文核心期刊要目总览》化学类核心期刊,全国优秀科技期刊二等奖",中国科学院优秀科技期刊一等奖,中国期刊方阵"双百期刊"
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘（网络版）,荷兰文摘与引文数据库,美国剑桥科学文摘,中国中国科技核心期刊,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）
  • 被引量:606