为了降低乙酸乙酯工业生产的能耗,提高产品收率,进行渗透汽化法分离水溶液中低质量分数乙酸乙酯的研究.采用实验室自制的聚二甲基硅氧烷(PDMS)/陶瓷复合膜,考察乙酸乙酯的质量分数和原料液温度对渗透汽化性能的影响.研究发现,当原料液中乙酸乙酯的质量分数为7%、温度为50℃时,膜的渗透通量和分离因子分别达到8.7 kg/(m^2·h)和38.1.在分离因子相当的前提下,聚二甲基硅氧烷/陶瓷复合膜的渗透通量与其他报道的膜材料相比具有明显的优势.
A laboratory prepared polydimethylsiloxane(PDMS)/ceramic composite membranes was used to separate ethyl acetate (EtAc) from pervaporation of low-concentration aqueous solution to reduce the energy consumption and improve the yield. The effects of feed concentration and temperature on the separation performance were investigated. A high flux of 8.7 kg/( m^2·h) and a separation factor of 38.1 were obtained with the feed concentration of 7% at 50 ℃. Under the condition of comparative separation factor, the flux of PDMS/ceramic composite membranes was much higher than those of the other reported membranes.