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中文摘要：
近年来．具有特定拓扑结构超分子化合物的合成、结构和性质的研究引起化学工作者的浓厚兴趣，成为一个热门的研究领域。随着超分子化学理论研究的不断深入和配位聚合物在分子识别、分子材料和分子器件等方面的研究和开发中日益广泛的应用．使配位聚合物的研究成为设计和组装各种光、电、磁、离子交换、催化等新型功能材料的主要合成策略。由配位聚合物合成的这些功能材料具有许多特殊的性能，因而在选择性催化、分子识别、超高纯度分离、新型半导体材料、磁性材料开发中显示了诱人的应用前景。在合成这类超分子配位聚合物时，常选用含N、O、S、P等有较强的给电子能力的原子的有机配体去构建具有新颖的一维、二维、三维过渡金属配位聚合物。具有较强配位能力的吡啶和羧酸类的有机配体在设计合成配位聚合物时经常被用到，如4，4′-联吡啶，芳香羧酸及其衍生物等。
英文摘要：
A novel coordination ploymer [Cd（HO-BDC）（phen）·H2O]n （where HO-BDC is 5-Hydroxyisophthalic acid and phen is 1,10-phenanthroline） has been synthesized and characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. The crystal belongs to monoclinic, space group P2/c, with a=0.876 4 （2） nm, b= 1.233 0（3） nm, c=1.761 2（4） nm, β=109.152（9）°, V=1.797 8（7） nm^3, Z=4, Mr=490.73, Dc=1.813 g·cm^-3, F（000）= 976,μ=1.258 mm^-1, the final R=0.043 8 and wR=0.098 9 for 2 880 observed reflections with I〉2σ （I）. The structural analysis shows that the complex has a one-dimensional chain structure. CCDC： 609770.
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