以脲醛树脂(UF)为前驱体,经高温碳化和氢氧化钾溶液活化处理,制备脲醛树脂多孔碳(UFC),采用原位化学聚合法制备聚吡咯(PPy)/UFC复合材料。通过SEM、XRD和红外光谱等分析复合材料的形貌和结构特征;采用循环伏安、电化学阻抗和恒流充放电测试复合材料的电化学性能。PPy/UFC复合材料比单独的PPy和UFC具有更高的比表面积和更好的电化学性能,以4 A/g在-1.0-0 V循环,比电容为545 F/g,循环2 000次的电容保持率为91%。
Urea-formaldehyde resin (UF) derived porous carbon (UFC)was prepared by using UF as the precursor and activated with KOH solution. Polypyrrole(Ppy)/UFC composite was further prepared by in-situ chemical polymerization. The nanoeomposite was analyzed by SEM, XRD, Fourier-transform infraredspeetra(FTIR). The electrochemical performance of the nanocomposite was tested by cyclic voltammetry, electrochemical impedance spectroscopy (EIS)and galvanostatie charge-discharge. The Ppy/UFC composite had higher specific surface area and better electrochemical performance than single Ppy and UFC. When cycled in - 1.0 -0 V with 4 A/g,its specific capacitance was 545 F/S,the capacitance retention rate was 91% after 2 000 cycles.