中文摘要：

以钛酸四丁酯为钛源，离子液体1-丁基-3-甲基咪唑四氟化硼（[c4MIM]BF4）为辅助剂，采用水热法制备了锐钛矿相的介孔二氧化钛。用盐酸和氨水调节反应前驱体的pH，考察了pH在1～11变化范围内对离子液体一水制备二氧化钛体系的影响。采用X射线衍射和Nz吸附一脱附对样品的晶相和孔结构进行表征。结果表明：离子液体抑制了板钛矿二氧化钛的形成，随着pH的增大样品的晶化程度增强。pH在1～9较大范围变化时，其孔径分布较窄，平均孔径随pH增大由6．6nm减小到5．0nm，此时离子液体能较好的将样品粒径控制在9nm左右。这与透射电镜分析结果相一致。

英文摘要：

The mesoporous anatase TiO2 material was prepared by ionic liquid-assisted hydrothermal method using tetrabutyl titanate as titanium source and ionic liquid 1-butyl-3-methylimida-zolium tetrafluoroborate （[C4MIM]BF4） as template. The pH values of the starting suspensions were adjusted from 1 to 11 using HC1 or NH3＂H20 solution. The influence ofpH on the ionic liquid-water system for the preparation of titanium dioxide was investigated. The obtained TiO2 samples were characterized with X-ray diffraction （XRD） and N2 adsorption-desorption measure- ments, respectively. The results showed that the addition of ionic liquid inhibited the formation of the brookite TiO2, and increasing pH values enhanced the crystallization. When the pH was changed at a wide range （pH=1-9）, the pore size distributions of the samples were relatively narrow, and the average pore diameter was reduced from 6.6 nm to 5.0 nm by increasing pH value. At the same time, the average size of the TiO2 nanoparticles in the samples was controlled at about 9 nm by using ionic liquid-assisted hydrothermal method. This is consistent with the results of the transmission electron microscopy （TEM） analyses.