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基于PVK的高色纯度高稳定性有机电致红光器件
  • ISSN号:1000-7032
  • 期刊名称:发光学报
  • 时间:0
  • 页码:728-733
  • 语言:中文
  • 分类:TN383.1[电子电信—物理电子学] TN873.3[电子电信—信息与通信工程]
  • 作者机构:[1]河北大学物理科学与技术学院,河北保定071002
  • 相关基金:基金项目:国家自然科学基金(60678006);河北省博士基金(06547002D-4);河北省自然科学基金(E2007000196)资助项目
  • 相关项目:磷光PLED体系三重态激子扩散与发光的超快动力学研究
作者: 杨少鹏|
中文摘要:

利用旋涂法和真空蒸镀法相结合的方法,根据能量空间传递的原理制备了PVK∶Ir(piq)2(acac)体系的红色有机电致发光显示器件。器件的结构为ITO/CuPc/PVK∶Ir(piq)2(acac)/BCP/Alq3/LiF/Al。研究了不同主客体掺杂比对器件发光性能的影响,得到了高色纯度、单色性较好的红光器件。当Ir(piq)2(acac)掺杂的质量比为1∶0.08时,器件的综合性能达到最佳,发光峰位于625nm,CIE坐标为(x=0.66,y=0.33)。通过对各层厚度的合理选择,形成相对优化的微腔结构,充分利用其对光谱的窄化效应,使得器件的EL光谱的发射半峰全宽仅为55nm,提高了器件的发光性能。器件光谱具有很好的单色性,色纯度达到98.2%。

英文摘要:

Since Tang and VanSlyke developed an efficient organic light-emitting diode (OLED) based on an organic bilayer structure in 1987, the efficiency has been increased, particularly, the use of n- and p-doped organic transport materials with small-molecule OLEDs leads to improving conductivities and significantly better injection of charge carriers into the OLED. Further concepts have been established such as the insertion of additional organic layers as exciton and charge carrier blockers which can localize the emission zone and prevent exciton quenching effects as well as charge carrier imbalance. In spite of rapid advances in the organic electroluminescent device (OELD), there have still been many hurdles to be overcome for manufacturing a high-resolution full color display. The development of a stable, efficient, and saturated red device remains an important goal for OLEDs which is obtained by using a discrete emitting layer or doping fluorescent and phos- phorescent dyes into a host layer. In this report, a organic red electroluminescent device was fabricated based on hole transporting material PVK doped with Ir(piq) 2 (acac) by the spin-coating method and vacuum evapo- rate plating technology. The structure of the device is ITO/CuPc/PVK: Ir(piq) 2 (acac)/BCP/Alq3/LiF/AI. The effect of the doping ratio on the performance of the device was investigated. The device has high perfor- mance when the doping ratio is 1:0.08 in mass that the CIE coordinate is located at (x =0.66,y =0.33) and the main emission peak is at 625 nm. The full width at half maximum of the spectrum is only 55 nm. It is attributed to the structure of micro-cavity which is improved by the reasonable thickness of films. The color of a dye can be modified by inserting it into a microcavity. Indeed, a microcavity is formed within a OLED by weak reflections from interfaces. The spectrum of the device has fine monochromaticity that the color purity is 98.2%. The luminescence performance of the device is well improved.

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期刊信息
  • 《发光学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国物理学会发光分会 中国科学院长春光学精密机械与物理研究所
  • 主编:申德振
  • 地址:长春市东南湖大路3888号
  • 邮编:130033
  • 邮箱:fgxbt@126.com
  • 电话:0431-86176862
  • 国际标准刊号:ISSN:1000-7032
  • 国内统一刊号:ISSN:22-1116/O4
  • 邮发代号:12-312
  • 获奖情况:
  • 物理学类核心期刊,2000年获中国科学院优秀期刊二等奖,中国期刊方阵“双效”期刊
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  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:7320