欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
中文摘要：
由于具有很强的毒性，氰根离子的识别与检测在生命科学、环境科学等领域具有重要的意义。在众多的氰根离子检测方法中，基于主客体作用的氰根离子比色、荧光传感器由于其方法简单和灵敏度高、操作简便、成本较低等优点，逐渐成为人们关注的焦点。本文综述了2006年以来的氰根离子比色、荧光传感器的研究进展。根据传感器分子与氰根离子作用方式的不同，本文将氰根离子传感器分为6类：（1）氢键作用型氰根离子传感器。此类传感器分子通过氢键作用结合氰根离子从而实现对氰根离子的识别。（2）脱质子型氰根离子传感器。此类传感器分子通过氰根离子夺取传感器分子中的活泼氢，导致传感器分子发生分子内电子转移，从而实现对氰根离子的识别。（3）加成反应型氰根离子传感器。此类传感器分子通过与氰根离子发生特定的反应而实现对氰根离子的识别，根据具体反应类型的不同，又将其分成了5小类进行总结和阐述。（4）配位作用型氰根离子传感器。此类传感器分子为金属配合物，氰根离子与传感器分子上的金属离子通过配位作用结合或者氰根离子竞争夺取传感器分子中的金属离子，从而实现对氰根离子的识别。（5）基于纳米技术的氰根离子传感器。（6）基于其他机理的氰根离子传感器。本文对这些类型的氰根离子传感器从设计原理、识别性能和机理等方面进行了介绍，并展望了该领域的研究方向。
英文摘要：
Because of the extreme toxicity of cyanide anions, the development of colorimetric and fluorescent sensors for the cyanide anion （CN-） has received considerable attention. Among numerous CN- sensors, the colorimetric or fluorescent sensors received more and more attention because these kinds of sensors possess a lot of advantages such as high sensitivity, does not require expensive equipment and easy to operate. This review article highlights advances in the research of colorimetric or fluorescent sensors for the cyanide anion after 2006. According to recognition mechanisms of these sensors, we grouped them into six categories, including hydrogen bond based CN- sensors, deprotonation based nano-material based CN- sensors, CN- sensors, addition reaction based CN- and the sensors based on other recognition sensors, coordination based sensors, mechanism. This review summarizes the main design principles, CN- recognition abilities of the sensors. The developing orientation for further research is presented.
同期刊论文项目
同项目期刊论文
Rationally designed anion-responsive-organogels: sensing F(-) via reversible color changes in gel-ge
A rapid selective colorimetric and ‘On–Off’ fluorimetric sensor for detecting Cu2+ ions in aqueous m
Synthesis of Copillar[5]arene by Co–oligomerization of Different Monomers and Its Application to Sup
A cationic water–soluble pillar[5]arene: synthesis and host–guest complexation with long linear acid
An easy prepared double naphthalene Schiff-base for highly selective sensing of cyanide via the dipo
A highly selective dual-channel chemosensor for mercury ions: utilization of the mechanism of intram
Rationally designed supramolecular organogel dual-channel sense F？ under gel–gel states via ion-cont
Selective fluorescent sensor for mercury(II) ion based on an easy to prepare double naphthalene Schi
A novel strategy for the design of smart supramolecular gels: controlling stimuli-response propertie
A reversible fluorescent chemosensor for Fe~(3+) and H_2PO_4~- with “on-off-on” switching in aqueous
Synthesis and Crystal Structures of a 1D Cu Coordination Polymer Based on Tetrakis[3-(carboxyphenyl)
A highly selective colorimetric sensor for Hg2+ based on a copper (II)complex of thiosemicarbazone i
A simple pincer-type chemosensor for reversible fluorescence turn–on detection of zinc ion at physio
Nitrophenylfuran–benzimidazole–based reversible alkaline fluorescence switch accurately controlled b
A ‘‘keto–enol tautomerization’’-based response mechanism: a novel approach to stimuli–responsive sup
Rewritable security display material and Cl？ sensor: Based on a bimetal competitive coordination con
A fluorescent and colorimetric chemosensor for dihydrogen phosphate ions based on 2-pyridine-1H-imid
A reversible and highly selective fluorescent probe for monitoring Hg2+ and iodide in aqueous soluti
Competitive coordination control of the AIE and micro states of supramolecular gel: an efficient app
Double metal ions competitively control the guest-sensing process: a facile approach to stimuli-resp
A Fluorescent Chemosensor for Dihydrogen Phosphate Ion Based on 2-[2-Hydroxy-4-(diethylamino) phenyl
Highly reversible “on–off–on” fluorescence switch and logic gate accurately controlled by pH based o
TICT–ICT state change mechanism based acetate fluorescent sensor act as an “Off–On–Off” switch and l
Copillar[5]arene–based supramolecular polymer gel: controlling stimuli–response properties through a
TICT–ICT state change mechanism based acetate fluorescent sensoract as an “Off–On–Off” switch and lo
Cadmium-induced supramolecular hydrogels: Reversible sol–gel transitions induced by EDTA and acid/ba
A highly selective dual-channel Hg2+ chemosensor based on an easy to prepare double naphthalene Schi
Highly selective fluorescent sensing for CN- in water: utilization of the supramolecular self-assemb
Mercapto thiadiazole-based sensor with colorimetric specific selectivity for AcO- in aqueous solutio
Cadmium-induced supramolecular hydrogels: Reversible sol–gel transitions inducedby EDTA and acid/bas
Multi-stimuli responsive metal-organic gel of benzimidazol-based ligands with lead nitrate and their
Colorimetric chemosensor and test kit for detection copper(II) cations in aqueous solution with spec
Selective Chemosensor of Fe3+ Based on Fluorescence Quenching by 2,2 '-Bisbenzimidazole Derivative i
A reversible fluorescent chemosensor for mercury ions based on 1H-imidazo[4,5-b]phenazine derivative
A naphtholic Schiff base for highly selective sensing of cyanide via different channels in aqueous s
A highly selective and sensitive chemosensor for instant detection cyanide via different channels in
Reaction-based Dual-Channel Ratiometric Chemosensor for Instant Detection Cyanide in Water with High
Syntheses, Crystal Structures and Properties of Three New Complex Constructed from 3,5-Dinitrobenzoi
A highly selective fluorescent chemosensor for iron ion based on 1H-imidazo [4,5-b] phenazine deriva
A silver-induced metal-organic gel based on biscarboxyl-functionalised benzimidazole derivative: sti
期刊信息
位置：