采用Lu2O3/TiO2/Nb2O5作为ZrO2热障涂层材料的稳定剂,研究Lu2O3/TiO2/Nb2O5共稳定ZRO2(15%LTNSZ)热障涂层材料在900℃、40m01%V2O5+60m01%Na2S04熔盐中的热腐蚀行为。结果表明:8%YSZ热障涂层材料热腐蚀2h后,t相ZrO2全部相变为m相ZrO2,热腐蚀产物为尺寸较大的YVO4晶体;15%LTNSZ热障涂层材料热腐蚀20h后,m相ZrO2的比例仅为5.5%,热腐蚀产物为尺寸较小的LuVO4晶体。与Y2O3稳定剂相比,Lu2O3/TiO2/Nb2O5稳定剂使ZrO2在40mol%V2O5+60mol%Na2S04熔盐中的抗热腐蚀性能提高1个量级以上。
Hot corrosion is one of the main destructive factors in thermal barrier coatings (TBCs) of ZrO2 stabilized by 8wt%W2O3 (8%YSZ), which comes as a result of molten salt effect on the coating-gas interface. In this study the hot corrosion behavior of Lu2O3/TiO2/Nb2O5 co-doped ZrO2 (15%LTNSZ) and 8%YSZ in molten salt of 40mol%V2O5+60mol%Na2SO4 was evaluated. The results show that the molten salt reacts with Y2O3 and causes complete transformation of tetragonal ZrO2 into monoclinic phase and production of large dendritic YVO4crystals for 8%YSZ TBCs at 900 ℃ for 2 h. For 15%LTNSZ TBCs at 900 ℃ for 20 h, the molten salt reacts with Lu2O3 difficultly and almost does not react with TiO2 and Nb2O5, and cause transformation of tetragonal ZrO2 of 5.5%volume fraction into monoclinic phase and production of small dendritic LuVO4 crystals. 15%LTNSZ has an outstanding hot corrosion resistance to molten salt of 40 mol%V2O5+60 mol% Na2SO4