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塔里木盆地和田1井中寒武统膏岩层段发现原生白云石
  • ISSN号:0371-5736
  • 期刊名称:《地质论评》
  • 时间:0
  • 分类:P578.61[天文地球—矿物学;天文地球—地质学]
  • 作者机构:[1]南京大学地球科学与工程学院,南京210093, [2]中国石化石油勘探开发研究院,北京100083, [3]中国科学院地质与地球物理研究所,北京100029
  • 相关基金:本文是国家科技重大专项(编号:2011ZX05005 002 008HZ)和国家自然科学基金青年基金资助项目(编号: 41203045)的成果. 致谢:中国地质大学(北京)于炳松教授提供塔里木盆地中寒武统沉积相的相关资料;样品测试过程中,蒙南京大学内生金属成矿机制研究国家重点实验室的张文兰教授细心指导;成文过程中,与南京大学地球科学与工程学院卢华复教授进行了有益讨论,作者深受启发;南京大学地球科学与工程学院的曹剑教授对本文初稿进行了仔细修改;审稿人提出了建设性意见.一并诚致谢忱!
中文摘要:

岩石学与地球化学研究表明,塔里木盆地和田1井中寒武统膏岩层中白云石为原生白云石。岩石学特征上,白云石晶体微小,属隐晶—微晶(〈5μm),呈他形—次圆形,并且不含灰质前驱物。白云石与自生石膏有密切联系,根据其与石膏的关系及岩石学特征,可以将其分为两类:A类原生白云石,包裹在石膏内,晶体较大,一般大于3μm;B类原生白云石,石膏分散在其中,具有极好的长柱状晶形,白云石晶体较小,一般小于3μm。地球化学特征上,两类白云石差别也较明显。A类白云石具有高的n(Mg)/n(Ca)比,平均为0.96,接近化学计量白云石。Na2O,SrO,FeO,MnO平均含量分别为160 μg/g, 270 μg/g, 2250 μg/g, 120 μg/g。δ^13C(PDB)与δ^18O(SMOW)平均值分别为0.3‰,24.6‰;与A类原生白云石相比,B类原生白云石n(Mg)/n(Ca)比较低,平均值为0.90。具有较高的Na2O, FeO,MnO含量与稍低的SrO含量,平均值分别为290 μg/g,2540 μg/g,200 μg/g,200 μg/g。δ^13C(PDB)与δ^18O(SMOW)变化不大,δ^13C稍低,平均值为-0.3‰,δ^18O值较高,平均值为25.2‰。研究表明,文中白云石为原生沉淀,而非交代前驱物灰岩形成,Mg的来源为强烈蒸发形成的高盐度咸水。微生物可能参与了白云石沉淀过程。

英文摘要:

Objectives: Dolomite, as an important type of sedimentary rock, has attracted significant research attention due to its significance in either science or industry. Despite research over than 200 years, the origin of dolomite still remains one of the most debated subject in sedimentary geology, as commonly termed as Dolomite Problem. Recent culture experiments have demonstrated that microbial mediation helps to overcome the kinetic barriers limiting the formation of dolomite; dolomite can precipitate from aqueous solutions under Earth surface conditions. However, the occurrences of primary dolomite in ancient rocks, especially in paleozoic rock records, have rarely been reported. In this study, we reported the observations of primary dolomite in the Middle Cambrian evaporate sequences (Awatage Formation) from Well Hetian-1 in Tarim Basin, NW China. The results will improve our knowledge on the origin of dolomite in geological past. Methods: We observed the well cores to investigate the lithology and distribution of dolomite. The properties of dolomite crystals were investigated by back scattered electron imaging and field emission scanning electron microscopy (LEO1530VP). The elemental compositions of dolomite were analyzed by a JEOL JXA8100 electron microprobe analyzer. The stable carbon and oxygen isotopic compositions of dolomite were analyzed by a MAT 252 mass spectrometer. Results: Petrographically, the dolomite is crypto-microcrystalline ( 〈 5 μm in diameter) and lacks any direct or indirect evidence of a precursor mineral. Based on the association between dolomite and gypsum and the petrography of dolomite, the dolomite occurs in two modes : (A) dolomite enwraped in gypsum with relative larger crystal of 〉 3 μm in size; and (B) gypsum bearing dolomite, the dolomite minerals are relative small, generally less than 3 μm. In addition, some sheet-like dolomites were observed, which can be interpreted as the mineralization of extracelluar polymeric substance (EPS). Geochemi

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期刊信息
  • 《地质论评》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学技术协会
  • 主办单位:中国地质学会
  • 主编:杨文采
  • 地址:北京阜成门外百万庄路26号中国地质学会期刊处
  • 邮编:100037
  • 邮箱:georeview@cags.ac.cn
  • 电话:010-68999804
  • 国际标准刊号:ISSN:0371-5736
  • 国内统一刊号:ISSN:11-1952/P
  • 邮发代号:2-382
  • 获奖情况:
  • 中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),美国地质文献预评数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:23413