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高稳定性金属有机配位聚合物膜的制备及二甲苯分离性能
  • ISSN号：0251-0790
  • 期刊名称：《高等学校化学学报》
  • 时间：0
  • 分类：O614[理学—无机化学;理学—化学]
  • 作者机构：[1]吉林大学化学学院,无机合成与制备化学国家重点实验室,长春130012
  • 相关基金：国家“九七三”计划项目（批准号：2012CB821700）和国家自然科学基金（批准号：91022030,21101072）资助.
作者： 康子曦[1], 薛铭[1], 范黎黎[1], 黄麟[1], 卫国英[1], 裘式纶[1]
关键词： 金属有机配位聚合物, 分离膜, 二甲苯同分异构体, 高稳定性
中文摘要：

以常见的多孔二氧化硅为载体，采用晶种一二次生长法在溶剂热条件下制备了高稳定性的金属有机配位聚合物膜材料．通过X射线衍射、扫描电子显微镜、单组分气体透过率和二甲苯同分异构体分离等测试手段对材料的结构、形貌和性质等进行了表征．二甲苯同分异构体的渗透汽化分离结果表明，这种多孔膜材料对二甲苯混合物具有选择性吸附分离的性质．进一步通过热处理、超声处理和性能的重复表征，证明了该膜材料具有优良的热稳定性和机械稳定性，适于实际应用．

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期刊信息
  • 《高等学校化学学报》
  • 北大核心期刊（2011版）
  • 主管单位:中华人民共和国教育部
  • 主办单位:吉林大学 南开大学
  • 主编：周其凤
  • 地址：吉林大学南胡校区
  • 邮编：130012
  • 邮箱：cjcu@jlu.edu.cn
  • 电话：0431-88499216
  • 国际标准刊号：ISSN：0251-0790
  • 国内统一刊号：ISSN：22-1131/O6
  • 邮发代号:12-40
  • 获奖情况:
  • 首届及第二届国家期刊奖,连续两届“百种中国杰出学术期刊”,中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘（网络版）,荷兰文摘与引文数据库,美国工程索引,美国科学引文索引（扩展库）,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）,英国英国皇家化学学会文摘,中国北大核心期刊（2000版）
  • 被引量:50676