位置：成果数据库 > 期刊 > 期刊详情页
Studies Toward the Synthesis of (R)-(+)-Harmicine
  • 期刊名称：Chin. J. Chem.
  • 时间：2012.10.10
  • 页码：2297-2302
  • 分类：O629.9[理学—有机化学;理学—化学] O625.42[理学—有机化学;理学—化学]
  • 作者机构：[1]Beo'ing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry andMolecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China
  • 相关基金：The project is supported by the National Natural Science Foundation of China （No. 21072009, 21172005）, National Basic Research Program of China （973 Program, No. 2009CB825300） and the Research Fund for the Doctoral Program of Higher Education （No 20090001120014）.
  • 相关项目：以钯卡宾为基础的催化反应研究
作者： Fanyang Mo|Fei Li|Di Qiu|Yan Zhang*|Jianbo Wang*|
关键词： 全合成, Wolff重排, 朝向, 对映选择性, 羰基化合物, 吡咯烷酮, 光诱导, 顺式, diastereoselective synthesis, （R）-（ ＋ ）-harmicine, diazo compounds, Wolff rearrangement,photo-induced reaction
中文摘要：

E-mail： wangjb@pku.edu.cn

同期刊论文项目
　惰性化学键的选择性激活、重组及其控制
期刊论文 24
　新型氮杂环卡宾在过渡金属催化重氮化合物反应中的应用研究
期刊论文 1
以钯卡宾为基础的催化反应研究
期刊论文 54
经由金属卡宾中间体的偶联反应机理研究及反应拓展
期刊论文 47
同项目期刊论文
Diazo Compounds and N-Tosylhydrazones: Novel Cross-Coupling Partners in Transition-Metal-Catalyzed R
Copper-catalyzed cascade coupling/cyclization of terminal alkynes with diazoacetates: a straightforw
Coupling of N-Tosylhydrazones with Terminal Alkynes Catalyzed by Copper(I): Synthesis of Trisubstitu
CuBr-Catalyzed Coupling of N-Tosylhydrazones and Terminal Alkynes: Synthesis of Benzofurans and Indo
硫叶立德[2,3]-σ重排反应迁移基团活性研究
Lewis Acid Catalyzed Direct Cyanation of Indoles and Pyrroles with N-Cyano-N-phenyl-p-toluenesulfona
Gold(III)-Catalyzed Direct Acetoxylation of Arenes with Iodobenzene Diacetate
Expeditious Synthesis of Phenanthrenes via CuBr(2)-Catalyzed Coupling of Terminal Alkynes and N-Tosy
Recent Developments in Pd-Catalyzed Reactions of Diazo Compounds
New Developments in Aromatic Halogenation, Borylation, and Cyanation
Palladium-Catalyzed Oxidative Cross-Coupling of N-Tosylhydrazones or Diazoesters with Terminal Alkyn
Catalytic Thia-Sommelet-Hauser Rearrangement: Application to the Synthesis of Oxindoles
Copper-Catalyzed Direct Benzylation or Allylation of 1,3-Azoles with N-Tosylhydrazones
A base-free, one-pot diazotization/cross-coupling of anilines with arylboronic acids
Sequential Au(I)-catalyzed reaction of water with o-acetylenyl-substituted phenyldiazoacetates
Pd-Catalyzed Carbonylation of Diazo Compounds at Atmospheric Pressure: A Catalytic Approach to Keten
Copper-Catalyzed C(sp(3))-C(sp(3)) Bond Formation Using a Hypervalent Iodine Reagent: An Efficient A
Palladium-catalyzed Cross-coupling of Aryl Iodides with beta-Trimethylsiloxy-alpha-diazoesters: A No
Synthesis of Pinacol Arylboronates from Aromatic Amines: A Metal-Free Transformation
Palladium-Catalyzed Diarylmethyl C(sp(3))-C(sp(2)) Bond Formation: A New Coupling Approach toward Tr
Copper-Catalyzed Direct Ortho-Alkylation of N-Iminopyridinium Ylides with N-Tosylhydrazones
Recent applications of arene diazonium salts in organic synthesis
Copper-Catalyzed Direct C-H Trifluoromethylation of Quinones
Transition-Metal-Catalyzed Cross-Coupling Reaction with N-Tosylhydrazones
Synthesis of Allyl Allenes through Three-Component Cross-Coupling Reaction of N-Tosylhydrazones, Ter
Catalyst-Free Imidation of Allyl Sulfides with Chloramine-T and Subsequent [2,3]-Sigmatropic Rearran
Palladium(II)-Catalyzed Direct Conversion of Methyl Arenes into Aromatic Nitriles
Synthesis of Aryl Trimethylstannanes from Aryl Amines: A Sandmeyer-Type Stannylation Reaction
Synthesis of Aryltrimethylstannanes from Arylamines: A Sandmeyer-Type Stannylation Reaction
Pd-Catalyzed Three-Component Reaction of Allenes, Aryl Iodides and Diazo Compounds: New Approach to
Catalytic Cascade Reactions Involving Metal Carbene Migratory Insertion
Pd-Catalyzed Cyclization and Carbene Migratory Insertion: New Approach to 3-Vinylindoles and 3-Vinyl
N-Tosylhydrazine-mediated deoxygenative hydrogenation of aldehydes and ketones catalyzed by Pd/C
Recent developments in copper-catalyzed reactions of diazo compounds
Silver-Mediated Trifluoromethylation of Aryldiazonium Salts: Conversion of Amino Group into Trifluor
Cross-Coupling Reactions Involving Metal Carbene: From C=C/C-C Bond Formation to C-H Bond Functional
经由三氟甲基自由基的三氟甲基化反应研究进展
Reaction of Diazo Compounds with Organoboron Compounds
Ru(II)-Catalyzed rearrangement of 2-aryl-2-(phenylthio)penta-3,4-dienyl 2,2,2-trichloroacetimidates
CuI-Catalyzed Cross-Coupling of N-Tosylhydrazones with Terminal Alkynes: Synthesis of 1,3-Disubstitu
Carbonylation of Metal Carbene with Carbon Monoxide: Generation of Ketene
Catalyst-Free Intramolecular Formal Carbon Insertion into sigma-C-C Bonds: A New Approach toward Phe
硫叶立德【2，3]-σ重排反应迁移基团活性研究
硫叶立德[2,3]-σ 重排反应迁移基团活性研究
Cu(I)-catalyzed reaction of diazo compounds with terminal alkynes: a direct synthesis of trisubstitu
Oxidative Cross-Coupling of Allenyl Ketones and Organoboronic Acids: Expeditious Synthesis of Highly
Palladium-catalyzed three-component reaction of N-tosylhydrazone, norbornene and aryl halide
Trifluoromethylthiolation of Diazo Compounds through Copper Carbene Migratory Insertion
Synthesis of 3-trifluoromethylpyrazoles via trifluoromethylation/cyclization of alpha,beta-alkynic h
Formal Carbene Insertion into C-C Bond: Rh(I)-Catalyzed Reaction of Benzocyclobutenols with Diazoest
Iron(II)-Catalyzed Direct Cyanation of Arenes with Aryl(cyano)iodonium Triflates
Conversion of Aromatic Amino into Trifluoromethyl Groups through a Sandmeyer-Type Transformation
Switchable 2,2,2-Trifluoroethylation and gem-Difluorovinylation of Organoboronic Acids with 2,2,2-Tr
Formal Carbon Insertion of N-Tosylhydrazone into B-B and B-Si Bonds: gem-Diborylation and gem-Silylb
硫叶立德【2，3]-σ重排反应迁移基团活性研究
二氧化碳作为羧化试剂用于羧酸及其衍生物的合成(英文)
钯催化苯乙烯类分子胺氟化反应研究
硫叶立德【2，3]-σ重排反应迁移基团活性研究
氮杂环卡宾双核金络合物催化的胺芳基化反应
小核糖核酸病毒抑制剂研究及WIN系列抗病毒化合物的发展
过渡金属催化碳氢键三氟甲基化
Privileged chiral catalysts in asymmetric Morita-Baylis-Hillman/ aza-Morita-Baylis-Hillman reaction
γ-取代的α-重氮β-羰基酯化合物的烯醇锂盐对N-亚磺酰亚胺的高度非对映选择性加成
Diastereoselective addition of lithium enolate of γ-substituted α-diazoacetoacetate to N-sulfinyl imines
氟离子对二氧化钛选择性光催化氧化环己烷的影响
环境污染物的光催化降解：活性物种与反应机理
Stereoselective Synthesis of 1-Aminocyclopropanecarboxylic Acid Derivatives via Ylide Cyclopropanation of Dehydroamino Acid Derivatives
Privileged strategies for direct transformations of inert aliphatic C–H bonds
经sp^2碳钯键向sp^3碳钯键迁移进行的烯丙基胺化反应
An unexpected palladium migration from vinylic sp2 carbon to allylic sp3 carbon
钯催化重氮化合物反应的研究进展
CO2-Triggered Metal Catalyst- and Solvent-free Aminochlorination of Methylenecyclopropanes
煅烧温度对花朵状钨酸铋光催化活性的影响
Pd（OAc）2-Catalyzed Tandem Reactions for the Synthesis of Indol-3-yl Substituted 1H-Isochromenes and 1,2-Dihydroisoquinolines
CuCl-Catalyzed Aerobic Oxidation of Allylic and Propargylic Alcohols to Aldehydes or Ketones with 1 ： 1 Combination of Phenanthroline and Bipyridine as the Ligandst
多相双金属Pt-Sn/γ-Al2O3催化的胺N-烷基化反应合成仲胺和叔胺
过渡金属催化的对甲苯磺酰腙的偶联反应
钌（Ⅱ）-吡啶基NNN配合物催化酮的室温（不对称）氢转移反应