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饮用水源中不同粒径颗粒物吸附抗生素特征研究
  • ISSN号:0253-2468
  • 期刊名称:环境科学学报
  • 时间:0
  • 页码:-
  • 分类:X131.2[环境科学与工程—环境科学]
  • 作者机构:[1]天津大学,环境科学与工程学院,天津300072, [2]天津工业大学.环境与化学工程学院,天津300387, [3]天津城建大学,环境与市政工程学院,天津300384
  • 相关基金:国家自然科学基金(No.51208353);国家水体污染控制与治理重大专项(No.2014ZX07203-009-02)
  • 相关项目:给水管网腐蚀层中稳态水对管网水质影响机制及调控方法
中文摘要:

天然水体中存在大量的细小颗粒,它们往往与污染物相互作用并成为其载体,在饮用水传统处理工艺中亦不能被很好去除,进而随水厂出水进入人体,对人体健康造成潜在威胁.抗生素在饮用水源中的固、液相分配规律以及不同粒径颗粒对抗生素的吸附能力及影响因素亟待研究.实验利用微波萃取(MAE)和高效液相色谱与质谱联用(HPLC-MS/MS)的方法分别对颗粒物上吸附的抗生素进行了前处理和测定,进而分析了饮用水源颗粒物对4种典型抗生素的吸附特征.连续吸附平衡实验在360 min达到平衡,平衡时抗生素有32%~44%分布在颗粒上;除青霉素外,粒径0.05~1μm小颗粒的吸附量又占颗粒总吸附量的56%~70%.同时p H是影响饮用水源中颗粒吸附抗生素的重要因素,无论对于所有颗粒还是0.05~1μm的小颗粒,其吸附能力的最大值均出现在中性条件(p H=7)下.

英文摘要:

A large number of small particles exist in natural water. They often interact with contaminants as their carrier, which are usually entering to the human body through drinking water and become a serious threat to human health. This study is conducted to investigate partitioning of antibiotics in nature water between liquid and soild phases, and the performance of antibiotics adsorption on particles with different physical-chemical properties. The adsorption of 4 kinds of typical antibiotics on the surface of the particles was analyzed. Element composition of the particles were concentrated with microwave extraction method and were analyzed by using environmental scanning electron microscopy and energy dispersive spectroscopy. HPLC-MS/MS (high performance liquid chromatography tandem mass spectrometry) was developed for simultaneous determination of 4 antibiotics. When the continuous adsorption experiments reached equilibrium in 360 min, 32%-44% of the antibiotic was distributed in solid phase. In addition to penicillin G, the adsorption of antibiotics on 0.05 - 1 ~xm particles accounted for 56% ~ 70% of the total adsorption amount. However, pH value has significant influence on particle adsorption capacity to antibiotics. All the particles reached the maximum adsorption under neutral pH. The experimental results have important implications for water quality improvement and increasing drinking water treatment processes.

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期刊信息
  • 《环境科学学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国科学院生态环境研究中心
  • 主编:汤鸿霄
  • 地址:北京2871信箱
  • 邮编:100085
  • 邮箱:hjkxxb@rcees.ac.cn
  • 电话:010-62941073
  • 国际标准刊号:ISSN:0253-2468
  • 国内统一刊号:ISSN:11-1843/X
  • 邮发代号:82-625
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰地学数据库,荷兰文摘与引文数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:56074