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中文摘要：
以Keggin型钛取代钨磷酸钾和醋酸银为反应物合成了1个新的多金属氧酸盐Ag4H3PTi2W10O40.16H2O（1）,通过X射线单晶衍射分析确定了其晶体结构,通过ICP分析和热重分析确定了其组成,通过红外光谱和固体漫反射光谱表征了其性质.单晶结构分析表明,化合物1属于四方晶系,I4/m空间群,晶胞参数a=b=1.39905（13）nm,c=1.14358（18）nm,V=2.2384（5）nm3,Z=2,R1=0.0550,wR2=0.1590.化合物1中的Ag＋均为六配位,每个Ag＋同时与3个多阴离子上的2个端氧和4个桥氧配位形成{AgO6}单元,这些{AgO6}将该多阴离子连接成三维网络结构.
英文摘要：
A new polyoxometalate compound, Ag4H3PTi2W10040 .16H20（1） , was synthesized with Keggin- type potassium dititanodecatungstophosphate and sliver acetate as raw materials. The produet was characterized by thermogravimetric analysis（ TGA）, infrared spectrum（ IR）, and solid diffuse reflectance spectrum（DRS）.
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