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中文摘要：
在室温下的乙醇体系中，设计合成了两种新型的含有水杨醛氨基乙酸席夫碱的配合物（C9H7NO3）Cu（C14H12N2）·H2O（1）和（C9H7NO3）Ni（C3H4N2）3·H2O（2）．这两个配合物分别通过元素分析、红外光谱和紫外光谱进行了表征，并用X射线衍射方法测定了它们的晶体结构．对于配合物1，中心金属铜处于四方锥构型环境，分子间经由氢键O4-H2W…O3，O4--H2W…O3^#1（#1：-x＋1，y，-z＋3／2）和弱的相互作用（π-π堆积）而连接成链结构；对于配合物2，中心金属镍处于八面体构型环境，通过两种分子内氢键：O-H…O和N-H…O，分子间氢键O8-HO14…O5^#1，O8-HO7…O3^#2和N3-H3A…O3^#3（#1：x-1，y，z；#2：x-1，y,z-1；#3：-x-2，-y＋1，-z＋2）形成氢键簇（每4个分子经由氢键连接成为一组）．
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