通过正交实验,研究了硅源(记为SiO2)、铝源(记为Al2O3)、磷源(记为P2O5)、模板剂(记为R)和水对SAPO-18分子筛合成的影响,根据极差分析得到各因素对SAPO-18分子筛合成的影响顺序为:P2O5〉Al2O3〉R〉H2O〉SiO2。结合单因素实验,确定合成SAPO-18分子筛初始凝胶的最优摩尔比为:0.9P2O5:0.8Al2O3:1.8R:50H2O:0.6SiO2。利用XRD、SEM和FTIR等检测技术对样品进行表征,并考察样品对甲醇制烯烃(MTO)反应的催化活性。结果表明,所得SAPO-18分子筛样品纯净,并具有优良的催化性能,在甲醇转化率100%的情况下,总低碳烯烃选择性为86.97%,而且产物中C2~C4烷烃以及C5+选择性较低。
The influence of five actors (SiO2, Al2O3, P2O5, template denoted R, H2O) on the synthesis of SAPO-18 zeolite were studied via orthogonal experiment. The primary and secondary factors have been analyzed via the method of range analysis, and the sequence is P2O5 〉 Al2O3 〉 R 〉 H20 〉 SiO2. Based on the single factor experiment, the synthesis gel with optimum molar composition of 0.9 P2O5 : 0.8 Al2O3 : 1.8 R : 50 H2O : 0.6 SiO2 was determined to produce SAPO-18. The synthesized SAPO-18 was characterized by XRD, SEM, FTIR and so on. The catalytic activity of SAPO-18 was evaluated for methanol to olefins reaction. The results showed that the pure SAPO-18 products were synthesized and the selectivity of light olefins (86.97%) was high and the selectivities of C2-C4 alkanes and C5+ were low in the MTO process.