采用两种离子液体1-烯丙基-3-甲基氯化咪唑([Amim]C1)与1-丁基-3-甲基氯化咪唑([Bmim]E1)分别与微晶纤维素(MCC)解结晶反应20、40与60min.X射线衍射技术(XRD)的分析结果表明,用[Amim]C1与[Bmim]C1处理MCC可使其结晶指数从90.2%分别降至72.4%与66.8%.x射线光电子能谱(XPS)的C1s、01s能谱峰分析显示,离子液体处理后,纤维素大分子中原有的化学键类型并没有明显改变,但相对含量有很大变化,C—OH键和C-OH…0键的相对含量变化均与结晶指数的变化高度相关,其相关系数分别为0.9990与0.9846.
Two kinds of ionic liquids, namely, 1 -allyl-3-methylimidazolium chloride ( [ Amim ] C1) and 1 -butyl-3- methylimidazolium chloride ( [ Bmim ] C1), were respectively used to decrystallize microcrystalline cellulose (MCC) for 20, 40 and 60 rain. XRD spectra show that, after the treatment with [ Amim ] C1 or [ Bmim ] C1, the crystalline index of MCC decreases from 90.2% to 72. 4% or to 66.8%. Moreover, XPS spectra indicate that, different from the relative content of chemical bonds, the chemical-bond type of cellulose macromolecules shows no obvious change after the decrystallization; and that the relative content changes of C--OH and C--OH…O are highly related to the variation of crystalline index, with the conelation coefficients being 0. 9990 and 0. 9846, respectively.