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Prediction of the internal energy contribution of polyethylene
  • 时间:0
  • 分类:TQ325[化学工程—合成树脂塑料工业]
  • 作者机构:1. Polymer Physics Laboratory, Center for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100080, China ,
  • 相关基金:This work was supported by the National Natural Science Foundation of China (Grant Nos. 29874035 and 20074041), the '863' High Technology Project, and the Special Funds for the State Major Basic Research Project (Grant No. G1999064800).
中文摘要:

Conformational elasticity theory recently developed has been used to explore the internal energy contribution to the elastic force fe/f as a function of strain for polyethylene (PE). Calculated fe/f values are in good agreement with those obtained experimentally. Results show that the behavior of fe/f is mainly contributed from intramolecular interaction of chemical structure, and that the internal energy contribution is strain-dependent.

英文摘要:

Conformational elasticity theory recently developed has been used to explore the internal energy contribution to the elastic force f e/f as a function of strain for polyethylene (PE). Calculated f e/f values are in good agreement with those obtained experimentally. Results show that the behavior of f e/f is mainly contributed from intramolecular interaction of chemical structure, and that the internal energy contribution is strain-dependent.

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