考察了水力停留时间(HRT)为10h时无排泥运行下膜-生物反应器(MBR)处理不同浓度氨氮无机废水的运行性能及微生物特性.结果表明,在处理NN4^+-N≤500mg/L的废水时,氨氮转化率可达99%且反应器内微生物增长缓慢,比硝化速率从0.2kg/(kg·d)升至0.52kg/(kg·d);当NH4^+-N≥700mg/L时,出水亚硝酸氮和氨氮相继出现明显累积,比硝化速率随之下降至0.4kg/(kg·d)以下,反应器内生物量从3200mg/L上升至6700mg/L.反应器中的氨氧化菌维持在10^7CFU/mL,亚硝酸盐氧化菌从10^6CFU/mL下降至10^3CFU/mL.系统内的溶解性微生物产物(以TOC表示)升至65mg/L后保持稳定,出水TOC一直维持在3-4mg/L;细胞外分泌物(EPS)在膜的截流作用下随运行时间的延长积累至600mg/L.
This work reports the results of performance and microbial characteristics in a membrane bioreactor (MBR) operated on inorganic ammonium-bearing wastewater for about 200 days at a hydraulic retention time (HRT) of 10 h and without sludge withdrawal. Under the conditions of ammonia concentration ≤ 500 mg/L, 99% NH4^+-N conversion rate could be achieved and biomass in the reactor changed little. The specific nitrification rate increased from 0.2 kg/(kg· d) to 0.52 kg/(kg· d). Accumulation of nitrite and ammonium appeared when the influent ammonia reached 700 mg/L, consequently the specific nitrification decreased to below 0.4 kg/(kg· d). However, although biomass in the bioreactor fleetly increased from 3 200 mg/L to the final 6 700 mg/L, the amount of ammonia oxidizers still kept at 10^7CFU/mL and the nitrite oxidizers decreased from 10^6CFU/mL to 10^3CFU/mL. Soluble microbial production (expressed as TOC) in the effluent was kept at around 3-4mg/L, while that in the reactor increased to 65 mg/L and then almost unchanged, Due to the interception of membrane, extracellular polymeric substrates (EPS) increased to 600 mg/L in the end.