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Hydrothermal Synthesis and Crystal Structure of [Mn（phen）-（m-phth）]n （phen=1 ,10-phenanthroline, m-phth=isophthalate）
  • ISSN号：1001-604X
  • 期刊名称：《中国化学：英文版》
  • 时间：0
  • 分类：O614.612[理学—无机化学;理学—化学] O614.511[理学—无机化学;理学—化学]
  • 作者机构：[1]中国科学院福建物质结构研究所结构化学国家重点实验室,福州350002, [2]中国科学院研究生院,北京100039
  • 相关基金：国家自然科学基金资助项目（No.90206040,20333070,20303021）;973资助项目（001CB108906）;福建省自然科学基金资助（No.2005HZ01-1）.
作者： 毕文华[1], 孙道峰[1], 曹荣[1], 李星[1], 时茜[1]
关键词： 2-羟基萘甲醛苯甲酰腙, 钼和钒, 合成和结构, 2-hydroxy naphthaldehyde benzoylhydrazone, molybdenum and vanadium, synthesis and structure
中文摘要：

2-羟基萘甲醛苯甲酰腙（H2L）由2-羟基萘甲醛和苯甲酰肼在乙醇溶液中制得.利用H2L分别合成了钼和钒的配合物,[MoO2（EtOH）L]（1）和[VO（OMe）L（MeOH）]（2）,并测定了它们的晶体结构.配合物1和2是类似的结构单元,钼和钒都采取扭曲的八面体配位构型.

英文摘要：

The new aroyl-hydrazone ligand, 2-Hydroxy naphthaldehyde benzoylhydrazone （H2L）, was prepared by the reaction of 2-Hydroxy naphthaldehyde and benzoyhydrazine in an ethanol solution. Two complexes, [MoO2（EtOH）L]（1） and [VO（OMe）L（MeOH）]（2）, based on the H2L ligand have been synthesized and characterized by single crystal X-ray diffraction analysis. Complexes 1 and 2 exhibit analogous structural units, the metal atom in which has a distorted octahedral coordination geometry. CCDC： 298811 （1）, 298810 （2）.

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期刊信息
  • 《中国化学：英文版》
  • 主管单位:
  • 主办单位:中国化学会
  • 主编：
  • 地址：上海市枫林路354号中科院上海有机化学研究所
  • 邮编：200032
  • 邮箱：
  • 电话：021-54925243
  • 国际标准刊号：ISSN：1001-604X
  • 国内统一刊号：ISSN：31-1547/O6
  • 邮发代号:4-646
  • 获奖情况:
  • 中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 美国化学文摘（网络版）,荷兰文摘与引文数据库,美国科学引文索引（扩展库）,日本日本科学技术振兴机构数据库,英国英国皇家化学学会文摘
  • 被引量:175