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滇池典型陆生和水生植物溶解性有机质组分的光谱分析
  • ISSN号:1001-6929
  • 期刊名称:环境科学研究
  • 时间:2013
  • 页码:72-79
  • 分类:X173[环境科学与工程—环境科学]
  • 作者机构:[1]南京师范大学地理科学学院,江苏南京210023, [2]中国环境科学研究院,环境基准与风险评估国家重点实验室,北京100012, [3]北京师范大学水科学研究院,北京100875
  • 相关基金:国家重点基础研究发展计划(973)项目(2008CB418200);中央级公益性科研院所基本科研业务专项(2010KYYW04);国家自然科学基金项目(41173094)
  • 相关项目:滇池流域土地利用/覆被变化对侵蚀产沙响应和生态环境影响的示踪研究
中文摘要:

应用紫外-可见光谱、傅里叶红外光谱与三维荧光光谱,对采自滇池外海及湖滨农田的2种典型陆生植物(玉米、紫茎泽兰)和5种水生植物(芦苇、水红花、水葫芦、眼子菜、茭草)所提取的DOM(溶解性有机质)组分进行了光谱分析.结果表明,陆生与水生植物DOM的紫外-可见光谱曲线基本类似,吸光度均随波长的增加而降低.陆生植物DOM的SUVA254(单位溶解性有机碳浓度下波长254 nm处吸收系数)值大于水生植物,表明滇池外源输入的DOM腐殖化程度大于内源.植物叶中DOM的A250/A365(A250、A365分别为波长250和365 nm处的紫外吸光度比值)小于茎,表明叶中DOM的芳香性和分子量都大于茎.陆生与水生植物DOM均有相似的红外特征峰带,其中—COO-、—CH2、—C=O、—OH、—NH2的特征峰明显,表明它们是构成陆生和水生植物DOM的主要官能团.三维荧光光谱分析表明,陆生植物茎的DOM中含有类富里酸物质,而叶的DOM中含有类腐殖酸物质.水生植物除了水葫芦叶的DOM中含有类腐殖酸物质外,其他样品无论茎、叶都含有类富里酸物质.除水葫芦叶外,同种植物茎的DOM中存在类色氨酸物质,而叶中不存在.

英文摘要:

By using UV-vis, Fourier transform infrared (FT-IR) and the three-dimensional excitation emission matrix fluorescence (3D- EEM) spectroscopies, chemical structures of water dissolved organic matters (DOM) were extracted from typical terrestrial and aquatic plants in or around the Dianchi Lake were investigated. The results showed that characters of UV-visible spectra were similar between the DOMs derived from the terrestrial and the aquatic plants. The ultraviolet absorbance of DOM samples decreased monotonically with increases of the wavelength. The SUVA2s4values of DOM derived from terrestrial plants were greater than those from aquatic plants, which indicated the higher humifieation degree of the DOM from the terrestrial. Ratios of A250 and A3650f the leaf DOMs were less than those of the stems, which illustrated that both aromaticity and molecular weight of leaf DOMs were higher than those of stem DOMs. The characteristic peaks of-CO0 - , -CH2 , -C =O, -OH and --NHzwere clearly shown in DOMs for both terrestrial and aquatic plants,and suggested that they would be the main function groups in DOMs of these species. The 3D-EEM spectrum showed that the DOMs from stems of the terrestrial plants contained fulvic acid and those from leaves have humic acid for these species. DOMs of stems and leaves of aquatic plants mainly contained fulvic acid, except the water hyacinth which had humic acid in its DOM. Except for the water hyacinth, DOMs from stems of all plants contained the tryptophan-like organic matters, but there were nosimilar fluorophore showed in their leaf DOMs.

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期刊信息
  • 《环境科学研究》
  • 中国科技核心期刊
  • 主管单位:中华人民共和国环境保护部
  • 主办单位:中国环境科学研究院
  • 主编:刘鸿亮
  • 地址:北京安外大羊坊8号中国环科院内
  • 邮编:100012
  • 邮箱:hjkxyj@163.com
  • 电话:010-84915128
  • 国际标准刊号:ISSN:1001-6929
  • 国内统一刊号:ISSN:11-1827/X
  • 邮发代号:82-384
  • 获奖情况:
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),英国农业与生物科学研究中心文摘,波兰哥白尼索引,荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,英国动物学记录,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国国家哲学社会科学学术期刊数据库,中国北大核心期刊(2000版)
  • 被引量:33433