研究了以尿素作沉淀剂,十二烷基硫酸钠作表面活性剂,采用均匀沉淀法制备纳米ZnO并采用静态试验法研究纳米ZnO吸附溶液中U(Ⅵ)的性能,考察了溶液pH、固液质量体积比、反应温度、接触时间和U(Ⅵ)初始质量浓度对纳米ZnO吸附溶液中U(Ⅵ)的影响。结果表明:纳米ZnO对溶液中的U(Ⅵ)有较好的吸附效果;室温下,纳米ZnO吸附U(Ⅵ)的最佳条件为溶液pH-6.0,接触时间80min,固液质量体积比0.5g/L,U(Ⅵ)初始质量浓度30mg/L;最佳条件下,纳米ZnO对U(Ⅵ)的吸附率达(96.32±1.47)%,吸附量为(57.79±0.89)mg/g,其吸附行为符合Freundlich和Temkin等温吸附模型,吸附机制为不均匀多层吸附为主、表面单层吸附为辅。
Using CO(NH2)2 as precipitator and twelve prepared by homo-precipitator method. The ZnO was alkyl Na2SO4 as surfactant,nano scale-ZnO was used to adsorb U(Ⅵ) in aqueous solution. The effects of solution pH, contacting time, temperature, solid-to-liquid ratio and initial concentration of U(Ⅵ) in the aqueous solution on adsorbing of U(Ⅵ) were examined, and the adsorption isotherms were analyzed. The results show that the nano scale-ZnO has very good adsorbing effect for U(Ⅵ ). At room temperature(298 K),the best adsorption conditions are the solution pH of 6.0,the contact time of 80 min,the solid-to-liquid ratio of 0.5 g/L,the initial U(Ⅵ) concentration of 30 mg/L,the removal rate and adsorption capacity for U ( Ⅵ ) reach (96. a2 ± 1. 47) % and (57. 7 ± 9 0. 89) mg/g, respectively. Adsorption isotherms follow with both Freundlich and Temkin, so the adsorption reactions mainly belong to heterogeneous multilayer adsorption and monolayer adsorption.