为了探讨岩浆侵入对煤结构参数的演化规律,对淮南煤田朱集区13—4钻孔内岩浆接触带两侧的4个煤样品进行了X射线衍射和激光共焦显微拉曼光谱测试和分析。结果表明:煤的XRD光谱均显示出较高的背景强度,在26°与42°附近出现明显的石墨衍射峰;煤的拉曼光谱在1000-2000cm-1波数范围内有两个明显的振动峰,分别为宽缓的D峰(1328-1369cm-1)和尖锐的G峰(1564-1599cm-1)。在岩浆侵入的影响下,煤结构参数的变化与煤级的变化有很好的相关性。
The structural parameters evolution of coal due to the influence of intrusions of hot magma was investigated and ana- lyzed. X-ray diffraction and laser confocal microscope Raman spectroscopy were used to test and analyze 4 coal samples undergo- ing varying contact-metamorphism by igneous magmas in borehole No. 13-4 of Zhuji coal mine, Huainan coalfield. The result showed that coal XRD spectrum showed higher background intensity, with the 26° and 42°nearby apparent graphite diffraction peak. Two significant vibration peaks of coal Raman spectra were observed in the 1 000-2 000 cm-1 frequency range: broad "D" peak at 1 328-1 369 cm i and sharp "G" peak at I 564-1 599 cm-1. With the influence of magma intrusion, the relation- ship between coal structural parameters and coal ranks was excellent.