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中文摘要：
采用等温蒸发法研究了五元体系Li^＋,K^＋//CO3^2-,SO4^2-,B4O7^2--H2O在288K时的介稳相平衡关系,测定了该五元体系在288K条件下的介稳平衡的溶解度和溶液密度,根据实验数据绘制了相应的介稳平衡相图和水图.相平衡研究结果表明该五元体系介稳相平衡中有复盐K2SO4·Li2SO4生成,其介稳相图（Li2CO3饱和）有4个共饱和点,9条单变量曲线,6个Li2CO3饱和的结晶区分别为LiBO2·8H2O,K2B4O7·4H2O,K2CO3·3/2H2O,K2SO4,Li2SO4·H2O和复盐K2SO4·Li2SO4.
英文摘要：
An experimental study on metastable equilibria at 288 K in the quinary system Li^＋,K^＋//CO3^2-,SO4^2-,B4O7^2--H2O was done by an isothermal evaporation method. Metastable equilibrium solubilities and densities of the solution were determined experimentally. Using the experimental data, the metastable equilibrium phase diagram and water diagram were plotted, respectively. The experimental results of the metastable equilibria show that the double salt K2SO4？Li2SO4 has been formed in the quinary system Li^＋,K^＋//CO3^2-,SO4^2-,B4O7^2--H2O at 288 K. In the metastable equilibrium phase diagram （saturated with Li2CO3）, the quinary system has four invariant points, nine univariant curves, six fields of crystallization saturated with Li2CO3 [LiBO2·8H2O, K2B4O7·4H2O, K2CO3·3/2H2O, K2SO4, K2SO4·Li2SO4 and Li2SO4·H2O].
同期刊论文项目
同项目期刊论文
Studies on Mean Activity Coefficients of KBr in KBr- K2SO4- H2O Ternary System at 298.15K by EMF Met
Liquid-Solid Equilibria in the Quaternary systems KCl - KBr - K2B4O7 - H2O and KCl - KBr - K2SO4 - H
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