采用简单的水热反应合成了新型棒状、棒束状和针状花型的四方相LaVO4:Dy3+晶体,用X粉末衍射(XRD)、扫描电镜(SEM)和荧光光谱(PL)分别测试了水热产品的物相结构、颗粒形貌和荧光性能.实验结果表明,前驱体浓度和反应温度对不同形貌LaVO4:Dy3+晶体的形成起到了关键作用。花状LaVO4:Dy3+晶体比棒状和棒束状样品具有更好的蓝黄比(B/Y),同时阐述了LaVO4:Dy3+同质异形体的形成机制.
Tetragonal LaVO4:Dy3+ with novel morphologies of rod,rod bundles and needle flower were successfully synthesized via a facile and surfactant-free hydrothermal process.The as-prepared samples were characterized by using X-ray diffraction(XRD),scanning electron microscopy(SEM),and photoluminescence spectroscopy(PL).The experimental results showed that the concentration of the precursor and the reaction temperature played important roles in morphological evolution of LaVO4:Dy3+nanocrystals (NCs).Moreover,flower-like LaVO4:Dy3+exhibited a higher B/Y value compared with nanorod and rod bundle LaVO4:Dy3+.Possible growth mechanisms of polymorphological LaVO4:Dy3+nanostructures were briefly discussed.