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Propane Dehydrogenation over PtSnNa Catalyst Supported on La-ZSM-5 Zeolite
  • ISSN号:1008-6234
  • 期刊名称:《中国炼油与石油化工:英文版》
  • 时间:0
  • 分类:TQ221.212[化学工程—有机化工] TE624.99[石油与天然气工程—油气加工工程]
  • 作者机构:[1]School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189
  • 相关基金:Acknowledgments: The authors are grateful to the National Nature Science Foundation of China (50873026), the Science and Technology Support Program of Jiangsu Province (BE2008129) and the "Six Talents Pinnacle Program" of Jiangsu Province (06-A-033) for financial supports.
中文摘要:

有 La 的不同内容的 La-ZSM-5 沸石被材料的物理化学的性质是的热水的 method.The 综合英尺红外分析的 studied.The 结果显示 La 可能被合并到分析显示出的 ZSM-5 zeolite.The NH3-TPD 的框架沸石的弱酸地点的数量与连续地增加的 La 减少了 content.Afterwards , La-ZSM-5 沸石被用作对丙烷 dehydrogenation.The 测试结果的 PtSnNa 催化剂的支持

英文摘要:

The La-ZSM-5 zeolite with different contents of La was synthesized by the hydrothermal method. The physico-chemical properties of the materials were studied. The results of FT-IR analyses indicated that La might be incorporated into the framework of ZSM-5 zeolite. The NH3-TPD analyses showed that the amount of weak acid sites of the zeolite decreased with a continuously increasing La content. Afterwards, the La-ZSM-5 zeolite was used as the support of PtSnNa catalyst for propane dehydrogenation. The test results revealed that the utilization of La- ZSM-5 zeolite could achieve a high propene conversion, and effectively inhibit the coke formation on the catalyst surface. When the content of La was 0.16%, the catalytic activity and stability of the catalyst got the best of its performance. Besides, the PtSnNa/La (0.16%)-ZSM-5 catalyst is more stable than the conventional PtSnNaLal ZSM-5 catalysts.

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期刊信息
  • 《中国炼油与石油化工:英文版》
  • 主管单位:中国石化集团公司
  • 主办单位:SINOPEC 石油加工研究所
  • 主编:汪燮卿
  • 地址:北京学院路18号
  • 邮编:100083
  • 邮箱:sylz@ripp-sinopec.com
  • 电话:010-82368292
  • 国际标准刊号:ISSN:1008-6234
  • 国内统一刊号:ISSN:11-4012/TE
  • 邮发代号:
  • 获奖情况:
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库)
  • 被引量:37