在四氢呋喃介质中,将1,5-环辛二烯氯化铱(I)二聚体([Ir(cod)Cl]2)与乙酰丙酮加热回流,一步合成了1,5-环辛二烯(乙酰丙酮)铱(Ⅰ)[Ir(acac)(cod)],产率88.6%.用元素分析、红外光谱(IR)和核磁共振(1H-NMR、^13C-NMR)等分析,结果表明产物为目标化合物.
Ir(acac)(cod)was synthesized in one-step process from [Ir(cod)Cl]2 in tetrahydrofuran by adding Hacac as the anion ligand. The yield was 88.6%. Structure of the complexes have been represented by the structural analytical methods like elemental analysis,1H-NMR, 13C-NMR, IR, then their chemical construction were confirmed finally.