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灰分对煤自燃特性影响的实验研究
  • ISSN号:1000-582X
  • 期刊名称:《重庆大学学报:自然科学版》
  • 时间:0
  • 分类:TD752.2[矿业工程—矿井通风与安全]
  • 作者机构:[1]重庆大学煤矿灾害动力学与控制国家重点实验室,重庆400030, [2]河南理工大学,河南焦作454000
  • 相关基金:国家自然科学基金青年基金资助项目(51204216); 博士点基金资助项目(20130191130003); 国家科技支撑计划资助项目(2012BAK04B09)
中文摘要:

为了研究灰分对煤自燃能力的影响作用,利用绝热氧化实验装置对不同灰分含量煤样进行升温氧化实验,采用R(70)、T(CPT)、B3种指标表征灰分含量对煤样自发氧化过程的影响。结果表明:1)灰分含量越大,煤样低温氧化阶段温升速率越小,温升加速点温度越高,煤样的自发氧化过程越慢,煤越不易自燃;灰分含量大于40%后,煤自燃倾向性快速减弱。温升加速点是反应微观信息的零活化能温度的宏观累计结果,具有直观且滞后的特点。灰分越大,滞后越明显,温差越大。2)R(70)、T(CPT)、B3种指标与灰分关系表现为二次函数。R(70)和T(CPT)两种指标显示灰分越大,自燃倾向性越弱,与实践经验相符。受水分权重影响,B指标显示煤样在灰分小于40%时,灰分越大,煤样自燃倾向性越强,这与实践经验相悖。因此,B在判定灰分对煤样自燃倾向性的影响时具有一定的局限性。

英文摘要:

In order to study the influence of ash on the ability of coal spontaneous combustion, we used coal samples with different ash content to carry out temperature rising oxidation experiments in adiabatic oxidation device, and characterized the effects of the different ash content on the coal spontaneous oxidation process with 3 indicators (R7o, TCPT, B). The results indicate that (1) the larger the ash content is, the slower the coal spontaneous oxidation process is. In low-temperature oxidation stage, the smaller the heating rate is, the higher the acceleration point of temperature-rising is and the more difficult the coal is to burn spontaneously. When the ash content is greater than 40%, the coal spontaneous combustion tendency is rapidly weakened. The acceleration point of temperature-rising is the accumulated results of temperature of zero-activation which reflects microscopic information, and it is intuitive and delayed. The larger the ash content is, the more obvious the lag is and the greater the difference in temperature is .(2) The relationship between ash content and the 3 indicators (R v0, Tcvr ,B) is quadratic function. R 70 and TcPw indicators show the larger the ash is, the weaker the coal spontaneous combustion tendency is, and that is in accordance with experience. Affected by the weight of water, B indicator shows when coal ash is less than 40%, the larger the ash content is, the stronger the coal spontaneous combustion tendency is, which is contrary to experience. Therefore, B indicator has certain limitations in the determination of the impact of ash on the coal spontaneous combustion tendency.

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期刊信息
  • 《重庆大学学报:自然科学版》
  • 中国科技核心期刊
  • 主管单位:国家教育部
  • 主办单位:重庆大学
  • 主编:王时龙
  • 地址:重庆市沙坪坝正街174号
  • 邮编:400044
  • 邮箱:cdxhz@equ.edu.cn
  • 电话:023-65102302
  • 国际标准刊号:ISSN:1000-582X
  • 国内统一刊号:ISSN:50-1044/N
  • 邮发代号:78-16
  • 获奖情况:
  • 中国高校精品科技期刊,重庆市一级期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),波兰哥白尼索引,荷兰文摘与引文数据库,美国剑桥科学文摘,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:26478