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中文摘要：
本文研究了羰基钼（钨）与双（1-甲基咪唑-2-基）甲酮和双（1-甲基咪唑．2-基）甲烷以及双（1-甲基咪唑-2-基）乙烯的反应，获得了6个双齿螯合的双（1-甲基咪唑-2-基）甲酮，双（1-甲基咪唑-2-基）甲烷和双（1-甲基咪唑-2-基）乙烯四羰基金属衍生物，以及1个单齿配位的双（1-甲基咪唑-2-基）乙烯五羰基钨化合物。它们的结构通过红外，核磁以及X-射线单晶衍射分析得到确证。所有这些新化合物的电化学测试表明，它们只存在一个不可逆的氧化过程。
英文摘要：
Reaction of bis （1-methylimidazole-2-yl）ketone [（mim）2C =O], bis （1-methylimidazole-2-yl）methane [（mim）2CH2] and bis（1-methylimidazole-2-yl）ethene [（mim）2C=CH2] with M（CO）5L （ M=Mo or W; L=CO or THF） has been investigated in this paper, which yields six bidentate chelating complexes （CO）4M（mim）2C=O, （CO）4M（mim）2CH2 and （CO）4M （mim）2C=Cn2 as well as a monosubstituted pentacarbonyl tungsten derivative （CO）5W （mim）2C=CH2. These complexes have been characterized by IR and NMR spectroscopy, and their structures have been further confirmed by X-ray crystal diffraction. The electrochemical behavior investigated by cyclic vohammetry indicates that these newly synthesized complexes exhibit one irreversible oxidative process.
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