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巢湖的稀土元素地球化学特征
  • 期刊名称:地球化学, 2006, 35(6): 639-644.
  • 时间:0
  • 分类:P595[天文地球—地球化学;天文地球—地质学] X142[环境科学与工程—环境科学]
  • 作者机构:[1]中国科学院地球化学研究所环境地球化学国家重点实验室,贵州贵阳550002, [2]中国科学院研究生院,北京100049, [3]云南大学资源环境与地球科学学院,云南昆明650091
  • 相关基金:中国科学院知识创新工程重要方向项目(KZCX3-SW-140和KZCXI-SW-12);国家自然科学基金(40573005);感谢中国科学院地球化学研究所张国平研究员在样品测试过程中给予的悉心指导;同时感谢中国科学院南京地理与湖泊研究所太湖生态系统研究站等单位在野外工作中提供的帮助.
  • 相关项目:Pu同位素法研究中国西南地区Pu的来源与沉降历史
中文摘要:

采用液-液萃取法和ICP-MS测试技术对巢湖的溶解态稀土元素进行了分析。结果表明,巢湖的溶解态稀土的含量与世界淡水相当,丰水期的样品含量高于其他季节。pH值和悬浮物、胶体是控制巢湖水体中溶解态稀土含量的主要因素。巢湖的溶解态稀土的分布模式以平坦型为主,少数呈现重稀土富集。丰水期和枯水期的溶解态稀土的(La/Yb)N值从西半湖区到东半湖区呈现有规律性的逐渐增大,并且丰水期的(La/Yb)N值低于枯水期。在富营养化湖泊中,胶体和水生生物可能是造成这一现象的主要原因。

英文摘要:

The dissolved rare earth elements (REEs) in the aquatic environment of Lake Chaohu were determined by inductively coupled plasma mass spectrometry (ICP-MS) after solvent extraction and back-extraction. The results show that the concentrations of dissolved REEs in Lake Chaohu are similar to those in freshwater of the world. Furthermore, these concentrations of dissolved REEs during high-water period are clearly higher than those during low-water season. The concentrations of dissolved REEs are mainly controlled by pH and the concentration of suspended and colloidal particles. The dissolved REEs in most lake waters show fiat NASC-normalized REE patterns, but a few samples showing heavy REE enrichment relative to NASC. The values of (La/Yb)N in highwater period and low-water season increase from west to east, and they in high-water period are larger than those in low-water season. These phenomena might be mainly resulted from colloidal particles and hydrophytes in the eutrophication lake.

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