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高氯酸根及其离子对光谱指认的量子化学研究
  • 期刊名称:光谱与光谱分析
  • 时间:0
  • 页码:2537-2540
  • 语言:中文
  • 分类:TQ252.3[化学工程—有机化工]
  • 作者机构:[1]河南师范大学化学与环境科学学院,新乡453007
  • 相关基金:国家自然科学基金项目(20703014); 河南省杰出青年基金项目(074100510005)资助
  • 相关项目:离子液体阴离子溶剂化行为的研究
中文摘要:

利用非等温、等温热重分析法,研究了高纯氮气气氛下1-烯丙基-3-甲基咪唑二氰胺盐([amim][N(CN)2])的热稳定性和平衡蒸汽压。非等温热重分析表明,其初始分解温度为551 K,而长期热重分析研究结果表明,[amim][N(CN)2]的最高可使用温度约为443 K。另外,利用基于热重的蒸发技术研究了该盐的平衡蒸汽压(Pe)与温度的关系并计算了标准蒸发焓。在423~473 K范围内,其Pe和温度的关系是:lgPe=14±1+(-(4.848±0.156)×103/T)。本文的结果为离子液体在高温下使用提供了理论依据。

英文摘要:

Thermal stability and equilibrium vapor pressure of 1-allyl-3-methylimidazolium dieyanamide ([amim] [ N (CN)2 ] ) were investigated by using both non-isothermal and isothermal thermogravimetric analysis (TGA) under high pure nitrogen as carrier gas. The non-isothermal TGA curve showed that the onset decomposition temperature was 551 K. However, the long-term isothermal TGA studies revealed that its highest use temperature should be 443 K. Moreover, the temperature dependence of the equilibrium vapor pressure and the standard enthalpy of vaporization of [amim] [ N(CN)2 ] were also investigated by TG-based transpiration.. In the temperature range of 423 -473K, the relationship between the equilibrium vapor pressure (Po) and temperature was lgPs = 14 ± 1 + - (4. 848 ±0.156) × 103 The results provided a theoretical basis for the usage of ionic liquid at high T temperature.

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