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Photodegradation of fluoroquinolone antibiotic gatifloxacin in aqueous solutions
  • ISSN号:0023-074X
  • 期刊名称:《科学通报》
  • 时间:0
  • 分类:X703[环境科学与工程—环境工程] TQ465[化学工程—制药化工]
  • 作者机构:[1]Key Laboratory of Industrial Ecology and Environmental Engineering (MOE), Department of Environmental Science and Technology,Dalian University of Technology, Dalian 116024, China
  • 相关基金:This work was supported by the National Basic Research Program of China (Grant No. 2006CB403302), National Natural Science Foundation of China (Grant No. 20777010) and the Program for Changjiang Scholars and Innovative Research Team in University of China (Grant No. IRT0813).
中文摘要:

Fluoroquinolone 抗菌素(FQ ) 经常在水的环境作为新兴的污染物质被检测。在 gatifloxacin 的 photodegradation 上的这研究,动力学,影响因素和机制,代表性的 FQ,被调查。photodegradation 跟随伪 first-order 动力学。有量收益的 Gatifloxacin photodegrades (5.94 摩 ????????????????? 溜??

英文摘要:

Fluoroquinolone antibiotics (FQs) are frequently detected as emerging pollutants in aqueous environments.In this study,kinetics,influencing factors and mechanisms on the photodegradation of gatifloxacin,a representative FQ,were investigated.The photodegradation follows the pseudo-first-order kinetics.Gatifloxacin photodegrades with a quantum yield of (5.94 ± 0.95) × 10 3 in pure water and undergoes direct photolysis as well as self-sensitized photodegradation.The FQ photodegrades slower in freshwater and seawater than in pure water,which is attributed to the integrative effects of pH and the aqueous dissolved matter (e.g.,humic acids and NO 3-) on the photodegradation.A toxicity test using Vibrio fischeri revealed the formation of hazardous photoproducts.

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期刊信息
  • 《科学通报》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学院
  • 主办单位:中国科学院
  • 主编:周光召
  • 地址:北京东黄城根北街16号
  • 邮编:100717
  • 邮箱:csb@scichina.org
  • 电话:010-64036120 64012686
  • 国际标准刊号:ISSN:0023-074X
  • 国内统一刊号:ISSN:11-1784/N
  • 邮发代号:80-213
  • 获奖情况:
  • 首届国家期刊奖,中国期刊方阵“双高”期刊,第三届中国出版政府奖
  • 国内外数据库收录:
  • 美国化学文摘(网络版),美国数学评论(网络版),美国工程索引,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:81792