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中文摘要：
采用金属有机物化学气相沉积技术在r面蓝宝石衬底上制备了a面GaN薄膜,用熔融的KOH在400℃对样品分别腐蚀1.0,1.5和2.0min.用扫描电镜、原子力显微镜、X射线衍射谱和阴极射线荧光对腐蚀前后的表面形貌进行分析.研究表明,400℃下腐蚀1.5min后出现了长平行四边形的条纹状,这是由于无极化的a面GaN表面极性各向异性,c向与m向上N原子悬挂键密度不同,同时稳定性不同,对OH-离子的吸附能力不同造成的,其中沿c方向易于腐蚀.同时,a面GaN腐蚀后出现了六角突起.我们认为这与穿透位错有关,而其形貌则与GaN薄膜的位错局部极性有关.
英文摘要：
On the substrate of r-sapphires a-GaN films grown by metal orgamic chemical vapor deposition was etched in molten KOH-NaOH for 1.0,1.5 and 2.0 min. Scanning electron microscope,atomic force microscope,X-ray diffraction and cathodoluminescence was used to study its morphology and defect. We find that etching for 1.5 min at the temperature of 400 ℃ is appropriate for a-GaN on sapphires substrate. Different from c-GaN which show hexagonal pits,a-GaN shows parallelogram strips. In the direction of c axis it is easier to be etched. That is because the polarity of a-GaN films is anisotropic which leads to different absorption capacities of OH ions in different directions. We also find hexagonal protuberance on the surface which is associated with threading dislocations.
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