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Effect of thermal pretreatment on the surface structure of PtSn/SiO2 catalyst and its performance in acetic acid hydrogenation
  • ISSN号:0438-1157
  • 期刊名称:《化工学报》
  • 时间:0
  • 分类:O625.11[理学—有机化学;理学—化学] TE624.93[石油与天然气工程—油气加工工程]
  • 作者机构:Key Laboratory for Green Chemical Technology of Ministry of Education, Collaborative Innovation Centre of Chemical Science and Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
  • 相关基金:Acknowledgements We are grateful to the financial support from the National Natural Science Foundation of China (Grant Nos. 21276186, 21325626, 91434127, U1510203) and the Tianjin Natural Science Foundation (13JCZDJC33000).
中文摘要:

活跃地点和在醋酸(AcOH ) 的 PtSn/SiO 2 催化剂的催化表演上的热预告的处理的效果加氢在这篇文章被调查。催化剂被 N 2 描绘物理吸附, X 光检查衍射,传播电子显微镜学, pyridine Fourier 变换红外线的系列,和它的物理化学的性质上的 H 2-O2 滴定。结果证明那磅种首先在水晶的结构被形成,没有 PtSn x 合金被观察。与热预告的处理温度的增长,同时,磅分散由于磅粒子的聚集显示出一个减少的趋势。同时,路易斯酸地点的数量被拥有到 Sn 种类的作为结果的物理化学的性质变化的如此的热预告的处理显著地影响。有趣地,催化活动与路易斯酸地点的显示出类似的变化趋势,证实在 AcOH 加氢的路易斯酸地点的重要角色。而且,在暴露的磅和路易斯酸地点之间的平衡效果被获得,在 AcOH 加氢导致优异催化表演。

英文摘要:

The effect of thermal pretreatment on the active sites and catalytic performances of PtSn/SiO2 catalyst in acetic acid (AcOH) hydrogenation was investigated in this article. The catalysts were characterized by N2 physical adsorption, X-ray diffraction, transmission electron microscopy, pyridine Fourier-transform infrared spectra, and H2-O2 titration on its physicochemical properties. The results showed that Pt species were formed primarily in crystalline structure and no PtSnx alloy was observed. Meanwhile, with the increment of thermal pretreatrnent temperature, Pt dispersion showed a decreas- ing trend due to the aggregation of Pt particles. Simultaneously, the amount of Lewis acid sites was remarkably influenced by such thermal pretreatment owning to the consequent physicochemical property variation of Sn species. Interestingly, the catalytic activity showed the similar variation trend with that of Lewis acid sites, confirming the important roles of Lewis acid sites in AcOH hydrogenation. Moreover, a balancing effect between exposed Pt and Lewis acid sites was obtained, resulting in the superior catalytic performance in AcOH hydrogenation.

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期刊信息
  • 《化工学报》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国化工学会 化学工业出版社
  • 主编:李静海
  • 地址:北京市东城区青年湖南街13号
  • 邮编:100011
  • 邮箱:hgxb126@126.com
  • 电话:010-64519485
  • 国际标准刊号:ISSN:0438-1157
  • 国内统一刊号:ISSN:11-1946/TQ
  • 邮发代号:2-370
  • 获奖情况:
  • 中国科协优秀期刊二等奖,化工部科技进步二等奖,北京全优期刊奖,中国期刊方阵“双效”期刊,第三届中国出版政府奖
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  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:35185