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阳离子型聚氨酯泡沫载体的制备及对活性污泥的吸附性能
  • ISSN号:1000-3304
  • 期刊名称:高分子学报
  • 时间:2012.6.1
  • 页码:679-684
  • 分类:TQ328.3[化学工程—合成树脂塑料工业]
  • 作者机构:[1]清华大学化工系教育部先进材料重点实验室,北京100084
  • 相关基金:国家高技术研究发展计划(863计划,项目号2009AA062903); 国家自然科学基金(基金号20874055,21174079)资助项目
  • 相关项目:以金属凝胶为模板聚合物一维纳米结构的合成及溶液自组装
中文摘要:

通过在聚氨酯泡沫塑料制备过程中加入不同用量的N-甲基二乙醇胺(简称N-MDA),并对聚氨酯泡沫进行酸化处理,得到了一系列阳离子型聚氨酯泡沫塑料(简称改性PUF),并对其结构和性能进行了研究.结果表明,以醋酸和磷酸(质量比为1∶1)作为N-MDA的催化抑制剂,可在较宽N-MDA用量范围内顺利合成改性PUF.随着N-MDA用量的增加,改性PUF的回弹率、拉伸强度及断裂伸长率均出现先增强后降低的趋势,而阳离子含量和亲水性不断增加.进一步将改性PUF作为固定化载体用于吸附活性污泥,结果显示,由于亲水性的增强和静电相互作用,改性PUF对活性污泥的吸附速度明显高于普通聚氨酯泡沫(简称对比PUF),其对活性污泥的单位体积吸附量最高可达180 g/L,是对比PUF(80 g/L)的2倍以上.

英文摘要:

A series of hydrophilic cationic polyurethane foams (defined as modified PUFs) were prepared by using N-methyl diethanolamine (defined as N-MDA) as the reactant and treating the foams by hydrochloric acid. The catalytic activity of N-MDA was effectively inhibited by using the mixture of phosphoric acid and acetic acid as the acidic inhibitor and the PUFs were successfully prepared at high amount of N-MDA. The structures and properties of the resulting samples were analyzed by IR spectrometer, contact angle measuring instrument, electronic stripping tester, conductivity meter and zeta potential meter. With increasing the amount of N-MDA,the cation content and hydrophilicity of the samples increased gradually,but the elastic resilience, tensile strength and elongation at break increased first and then decreased. Furthermore,The modified sample was used as a novel microorganism immobilized carrier for adsorbing activated sludge. The resuhs indicated that the modified PUF displayed a higher adsorption rate for activated sludge than the unmodified one (defined as contrast PUF). And its highest adsorption capacity for activated sludge could reach 180 g/L,more than two times of the capacity (80 g/L) of the contrast PUF. The adsorbing processes of these two carriers were explained based on the hydrophilieity of their backbone surfaces and the electrostatic attraction between the carrier and activated sludge. The improved adsorption property should make the modified PUF suitable for application in microbial immobilization.

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期刊信息
  • 《高分子学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国化学会 中国科学院化学研究所
  • 主编:张希
  • 地址:北京市海淀区中关村北一街2号
  • 邮编:100190
  • 邮箱:gfzxb@iccas.ac.cn
  • 电话:010-62588927
  • 国际标准刊号:ISSN:1000-3304
  • 国内统一刊号:ISSN:11-1857/O6
  • 邮发代号:2-498
  • 获奖情况:
  • 国家优秀期刊二等奖,中科院优秀期刊二等奖,中国科协优秀期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),英国高分子图书馆,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:19174