Three new polymer-supported NAD(P)H models (Ⅰ, Ⅱ, Ⅲ) were designed and synthesized, which can efficiently reduce many activated olefins under mild conditions.1 The most advantageous featureof the three NAD(P)H models is (i) easy work-up and separation of the reaction products and (ii) good potential for recycle use of the NAD(P)H models, which makes the three new polymer-supported NAD(P)H models a promising alternative both in research laboratories and in industrial processes.