室温条件下测定了Ba(Y1-xCe)2Si3O10(x=0.05,0.07,0.09)的漫反射吸收光谱、光声振幅谱和光声相位谱.由于高浓度掺杂使得ce3+与ce3+之间发生有效能量传递,从而导致Ba(Y1-xCe)2Si3O10(x=0.05,0.07,0.09)的漫反射吸收光谱强度依次降低,光声光谱强度依次增大.利用光声振幅谱结合相位谱的方法研究发光效率随掺杂浓度的变化,发现Ba(Y1-xCe)2Si3O10(x=0.05,0.07,0.09)3种不同掺杂浓度试样的发光效率依次降低.
The diffuse reflection absorption spectra, photoacoustic amplitude spectrum and photoacoustic phase spectrum of Ba(Y1-xCe)2Si3O10 (x = O. 05, O. 07,0.09 ) were measured at room temperature. The effective energy transmission between Ce3+ , which attributed to the high concentration doping of Ce3 + , led to the inten- sities of the diffuse absorption spectra decreased and the intensities of photoacoustic amplitude spectrum in- creased gradually with increasing doping density. Moreover, Ba(Y1-xCe)2Si3O10( x = 0. 05,0. 07,0. 09 ) samples with three different doping density (x = 0. 05 ,0. 07 ,0. 09 ) were experimented by using a new method of combining photoacoustic amplitude and phase information, and the results revealed that the luminous effi- ciencies of the samples decreased with increasing doping density.