文章用共沉淀法合成了铜锡复合氧化物光催化剂,并用X射线衍射(XRD),紫外-可见漫反射(UV-Vis)和透射电子显微镜(TEM)方法对不同焙烧温度下制得的CuO-SnO2纳米复合氧化物的物相组成、晶粒尺寸及光学性质进行了表征。以酸性蓝62染料溶液为模拟废水,在氙灯(模拟日光)光照下,对CuO-SnO2纳米复合氧化物的光催化活性进行了评价,考察了焙烧温度,焙烧时间和活性组分配比对其催化活性的影响。结果表明:在500℃焙烧3h制得的CuO-SnO2(Cu与Sn摩尔比1:1)纳米复合氧化物具有最高的光催化活性,同样条件下,其光催化活性比Degussa P25 TiO2提高约1.6倍。
The noval CuO-SnO2 nanocomposite photocatalysts were prepared by co-precipitation method. X-ray diffrac- tion, transmission electron microscopy and UV-Vis diffuse reflectance spectroscopy were employed to characterize the phase composition, particle size and optical absorption of the samples. Photocatalytic activity of CuO-SnO2 nano-composite oxide was assessed by using acid blue 62 as a simulated compound under the irradiation of Xe light. The effect of calcining tem- perature, calcining time and ingredient on catalytic activity was investigated. Results showed that the maximum specific ph0- tocatalytic activity was obtained on CuO-SnO2 nanocomposite calcined at 500℃ for 3h with mol rate of 1 : 1, which was much higher than that of Degussa P25 TiO2.