中文摘要：

采用温和的溶液法制备了五个掺杂过渡金属离子的含钕多酸化合物（TM=Mn（1），Co（2），Ni（3），Cu（4），Zn（5）），通过X-射线粉末衍射确定了这些化合物的晶相，并通过电感耦合等离子发射光谱、固体紫外一可见漫反射光谱等表征确定了过渡金属离子的掺杂。探讨了掺杂过渡金属离子对该系列化合物多色性质、光致发光性质、以及磁性质的影响。研究发现，过渡金属离子的掺杂对含钕多酸化合物有明显的着色效果，并且丰富了该系列化合物的多色性。

英文摘要：

Five Nd-contained POM complexes doped with transition metal were synthesized by adopting mild aqueous method （ TM = Mn （ 1 ）, Co （ 2 ）, Ni （ 3 ）, Cu （4）, Zn （ 5 ） ）. The structures of complexes were characterized by X-ray powder diffraction, and the presence of transition metal was confirmed by inductively coupled plasma optical emission spectrometry and solid-state UV-Vis diffraction spectrometry. The influence of transition metal dopant on multi-color properties, fluorescence, and magnetism were discussed as well. It was found that the complexes with dopant showed distinct tinctorial effect, and various multi-color effect.