以二茂铁和苯为原料采用CVD技术制备了定向、长为150~160μm铁/碳纳米管雷达波吸收剂,考察了反应温度、保温时间等对其生长状况的影响。采用扫描电镜(SEM)、高分辨透射电子显微镜(HRTEM)、X-射线光电子能谱(XPS)对所得产物进行了形貌、组成、结构表征。结果表明产物有较高的铁填充率,铁元素是以α-Fe晶型包覆在多壁碳纳米管中;吸收剂密度为2.4~2.6g/cm^3,电磁参数在2~18GHz范围内呈现良好的频散效应,低频段尤为显著。
Radar wave absorbents iron/carbon nanotubes(Fe/CNTs) were synthesized from benzene and ferrocene by CVD reactions. The materials were of aligned morphology with the tube length of 150~160 μm. The effects of reaction temperature and annealing time on the growth morphology were studied, and the surface morphology and microstructure of Fe/CNTs were analyzed by SEM, HRTEM and X-ray electron energy spectrum, Results showed α-Fe was encapsulated in multi-walled CNTs. The density of the absorbent was 2.4~2.6 g/cm^3. The materials showed complex permittivity of frequency dispersion in lower frequency between 2~18 GHz.