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浅叙工业废水高级氧化处理技术
  • ISSN号:1002-0721
  • 期刊名称:《中国稀土学报:英文版》
  • 时间:0
  • 分类:TQ426.96[化学工程]
  • 作者机构:[1]苏州科技学院材料化学与生物工程学院,苏州215009, [2]苏州科技学院江苏省环境功能材料重点实验室,苏州215009
  • 相关基金:Projects (21277094, 51478285, 21407111) supported by the National Natural Science Foundation of China; Projects (BK20140280,BK20151198) supported by the Natural Science Foundation of Jiangsu Province, China; Project (14KJA430004) supported by CollegiateNatural Science Fund of Jiangsu Province, China; Project supported by the Priority Academic Program Development of Jiangsu HigherEducation Institutions (PAPD), China; Project supported by Jiangsu Collaborative Innovation Center of Technology and Material forWater Treatment, China; Project supported Excellent Innovation Team in Science and Technology of Education Department of JiangsuProvince, China; Projects (SJHG1304, SJHG1310, SJHG1404) supported by the Jiangsu Key Laboratory for Environment FunctionalMaterials, China
中文摘要:

以棉花为模板、经硝酸铈溶液浸渍后煅烧,合成多孔结构的生物形态二氧化铈微管材料。采用场发射扫描电子显微镜(FESEM)、X射线衍射(XRD)、透射电子显微镜(TEM)、N2吸脱附程序升温还原(TPR)和CO氧化等手段对样品进行表征。结果表明,合成的材料是由尺寸约9nm的晶粒组成,复制出原模板的纤维形貌,比表面积(BET)为62.3m2/g。与传统CeO2微粒相比,在CO氧化实验中,所合成的材料表现出极高的催化活性。所合成的纤维状CeO2在320°C下CO的转化率约为90%,在410°C下CO的转化率达到100%。

英文摘要:

A biomorphic CeO2microtube with multiple-pore structure was fabricated by using the cotton as biotemplate,throughcerium nitrate solution infiltration and thermal decomposition.Field emission scanning electron microscope(FESEM),powder X-raydiffraction(XRD),transmission electron microscope(TEM),N2adsorption?desorption isotherms,temperature-programmedreduction(TPR)and CO oxidation were used to characterize the samples.The results indicated that the synthesized products werecomposed of crystallites with grain size about9nm and exhibited a fibrous morphology similar to the original template andpossessed a specific surface area(BET)of62.3m2/g.Compared with the conventional CeO2particles,the synthesized materialsshowed a superior catalytic activity for CO oxidation.For the synthesized fibrous CeO2,the CO conversion at320°C was above90%and a100%CO conversion was obtained at410°C.

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期刊信息
  • 《中国稀土学报:英文版》
  • 中国科技核心期刊
  • 主管单位:中国科协
  • 主办单位:中国稀土学会
  • 主编:徐光宪
  • 地址:北京新街口外大门2号
  • 邮编:100088
  • 邮箱:jrechina@263.net
  • 电话:010-62014832
  • 国际标准刊号:ISSN:1002-0721
  • 国内统一刊号:ISSN:11-2788/TF
  • 邮发代号:2-613
  • 获奖情况:
  • 优秀科技期刊奖,中国科协择优资助期刊,中国期刊方阵“双效”期刊
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  • 被引量:1055